ArticleChemical science2017
Template-directed synthesis of linear porphyrin oligomers: classical, Vernier and mutual Vernier.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Supramolecular template-directed synthesis of triazole oligomers.Chemical science · 2022Article
- Effect of backbone flexibility on covalent template-directed synthesis of linear oligomers.Organic & biomolecular chemistry · 2022Article
- Controlled mutation in the replication of synthetic oligomers.Chemical science · 2021Article
- Solid-Phase Synthesis of Sequence-Defined Informational Oligomers.The Journal of organic chemistry · 2020Article
- A Convenient Synthesis of Pentaporphyrins and Supramolecular Complexes with a Fulleropyrrolidine.Molecules (Basel, Switzerland) · 2019Article
- Sequence information transfer using covalent template-directed synthesis.Chemical science · 2019Article
- Transfer of Sequence Information and Replication of Diimine Duplexes.The Journal of organic chemistry · 2019Article
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2 authors.
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Abstract
Three different types of template-directed syntheses of linear porphyrin oligomers are presented. In the classical approach the product has the same number of binding sites as the template, whereas in Vernier reactions the product has the lowest common multiple of the numbers of binding sites in the template and the building block. Mutual Vernier templating is like Vernier templating except that both strands of the Vernier complex undergo coupling simultaneously, so that it becomes impossible to say which is the 'template' and which is the 'building block'. The template-directed synthesis of monodisperse linear oligomers is more difficult than that of cyclic oligomers, because the products of linear templating have reactive ends. All three types of templating are demonstrated here, and used to prepare a nickel(ii) porphyrin dodecamer with 4-pyridyl substituents on all twelve porphyrin units. The stabilities and cooperativities of the double-strand complexes involved in these reactions were investigated by UV-vis-NIR titration. The four-rung ladder duplex has a stability constant of about 2 × 10
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