ArticlePhotosynthesis research2017
Removal of the H subunit results in enhanced exposure of the semiquinone sites in the LM dimer from Rhodobacter sphaeroides to oxidation by ferricyanide and by O
Article in Photosynthesis research, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Preparation of Photo-Bioelectrochemical Cells With the RC-LH Complex FromFrontiers in microbiology · 2022Article
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Abstract
Bacterial reaction centers (RC) from Rhodobacter sphaeroides have been widely used to functionalize electrodes and to generate photocurrent. However, in most studies, direct electron transfer from the semiquinone to the electrode was not observed because the H subunit of the RC shields the semiquinone. It is demonstrated in the current work that removal of the H subunit effectively exposes the semiquinone sites in the LM dimer. This is demonstrated by measuring the second-order rate constant for the reaction between ferricyanide and the anionic semiquinone Q
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