ArticleOrganic letters2017
Total Synthesis of (+)-Pancratistatin by the Rh(III)-Catalyzed Addition of a Densely Functionalized Benzamide to a Sugar-Derived Nitroalkene.
Article in Organic letters, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 30 citations in OpenAlex.
- Visible-Light-Mediated Aerobic α-Oxygenation of Tetrahydroisoquinolines and Isoindolines Without External Photocatalysts.Molecules (Basel, Switzerland) · 2025Article
- Unveiling the Anticancer Potential: Computational Exploration of Nitrogenated Derivatives of (+)-Pancratistatin as Topoisomerase I Inhibitors.International journal of molecular sciences · 2024Article
- Short, enantioselective, gram-scale synthesis of (-)-zephyranthine.Chemical science · 2021Article
- Enantioselective Synthesis of Isocarbostyril Alkaloids and Analogs Using Catalytic Dearomative Functionalization of Benzene.Journal of the American Chemical Society · 2019Article
- RhIII-Catalyzed Synthesis of Isoquinolones and 2-Pyridones via Annulation ofEuropean journal of organic chemistry · 2018Article
- Synthesis of (+)-Pancratistatins via Catalytic Desymmetrization of Benzene.Journal of the American Chemical Society · 2017Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Herein, we report the concise total synthesis of (+)-pancratistatin, accessed in a 10-step linear sequence from commercially available inputs. The convergent synthesis features a highly diastereoselective Rh(III)-catalyzed C-H bond addition to a d-glucose-derived nitroalkene and a late-stage intramolecular transamidation to furnish the B ring lactam.
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Registered trials
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