ArticleScientific reports2017
Ionic Liquids: evidence of the viscosity scale-dependence.
Article in Scientific reports, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Design of Fluorine-Free Weakly Coordinating Electrolyte Solvents with Enhanced Oxidative Stability.Angewandte Chemie (International ed. in English) · 2025Article
- Efficient Selective COChemSusChem · 2025Article
- Ion Diffusion Reveals Heterogeneous Viscosity in Nanostructured Ionic Liquids.The journal of physical chemistry letters · 2024Article
- Flexibility is the key to tuning the transport properties of fluorinated imide-based ionic liquids.Chemical science · 2022Article
- Pressing matter: why are ionic liquids so viscous?Chemical science · 2022Article
- Article
- Conformational design concepts for anions in ionic liquids.Chemical science · 2020Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Ionic Liquids (ILs) are a specific class of molecular electrolytes characterized by the total absence of co-solvent. Due to their remarkable chemical and electrochemical stability, they are prime candidates for the development of safe and sustainable energy storage systems. The competition between electrostatic and van der Waals interactions leads to a property original for pure liquids: they self-organize in fluctuating nanometric aggregates. So far, this transient structuration has escaped to direct clear-cut experimental assessment. Here, we focus on a imidazolium based IL and use particle-probe rheology to (i) catch this phenomenon and (ii) highlight an unexpected consequence: the self-diffusion coefficient of the cation shows a one order of magnitude difference depending whether it is inferred at the nanometric or at the microscopic scale. As this quantity partly drives the ionic conductivity, such a peculiar property represents a strong limiting factor to the performances of ILs-based batteries.
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Registered trials
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