ArticleAngewandte Chemie (International ed. in English)2017
Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Bridging Chemical Literature and Molecular Graphs: LLM-Augmented Enantioselectivity Prediction for Iridium-Catalyzed Asymmetric C-H Borylation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Electrochemical Deoxygenative Silylation of Alcohols.Angewandte Chemie (International ed. in English) · 2025Article
- Development of Chiral Ligands for the Transition-Metal-Catalyzed Enantioselective Silylation and Borylation of C-H Bonds.Angewandte Chemie (International ed. in English) · 2022Review
- Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms.Chemical reviews · 2020Review
- Hydrogen Bond Directed ortho-Selective C-H Borylation of Secondary Aromatic Amides.Angewandte Chemie (International ed. in English) · 2019Article
- Iridium-Catalyzed Silylation of Unactivated C-H Bonds.Tetrahedron · 2019Article
- A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.Chemical Society reviews · 2018Review
- Iridium-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes.Angewandte Chemie (International ed. in English) · 2018Article
- Enantioselective C(spScience (New York, N.Y.) · 2018Review
- Desymmetrization of Diarylmethylamido Bis(phenols) through Peptide-Catalyzed Bromination: Enantiodivergence as a Consequence of a 2 amu Alteration at an Achiral Residue within the Catalyst.The Journal of organic chemistry · 2017Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The borylation of C-H bonds catalyzed by transition metals has been investigated extensively in the past two decades, but no iridium-catalyzed enantioselective borylation of C-H bonds has been reported. We report a set of iridium-catalyzed enantioselective borylations of aromatic C-H bonds. This reaction relies on a set of newly developed chiral quinolyl oxazoline ligands. This process proceeds under mild conditions with good to excellent enantioselectivity, and the borylated products can be converted to enantioenriched derivatives containing new C-O, C-C, C-Cl, or C-Br bonds.
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