Evidence map›Paper›PMID 28508520›Full record

ArticleAngewandte Chemie (International ed. in English)2017

Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air.

Indrek Kalvet, Theresa Sperger, Thomas Scattolin, Guillaume Magnin, Franziska Schoenebeck

Erratum issuedAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 28 papers.

0numbers the graph read from it
0cells of the map it votes in
28citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

28 citing papers in PubMed.

  1. Article
  2. Electrosynthetic C-O Bond Activation in Alcohols and Alcohol Derivatives.Angewandte Chemie (International ed. in English) · 2023
    Review
  3. Access to N-CFAngewandte Chemie (International ed. in English) · 2022
    Article
  4. Article
  5. Article
  6. Air-Stable PdAngewandte Chemie (International ed. in English) · 2022
    Article
  7. Review
  8. Reactivity of a Dinuclear PdOrganometallics · 2021
    Article
  9. Article
  10. Article
  11. Catalysis with Palladium(I) Dimers.Angewandte Chemie (International ed. in English) · 2021
    Review
  12. Article
  13. Efficient Pd-Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents.Angewandte Chemie (International ed. in English) · 2020
    Article
  14. Article
  15. Modular and Selective Arylation of Aryl Germanes (C-GeEtAngewandte Chemie (International ed. in English) · 2020
    Article
  16. N-Trifluoromethyl Hydrazines, Indoles and Their Derivatives.Angewandte Chemie (International ed. in English) · 2020
    Article
  17. Article
  18. Article
  19. Article
  20. Stereoselective CspAngewandte Chemie (International ed. in English) · 2020
    Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

5 authors.

Indrek KalvetInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.ORCID 0000-0002-6610-2857
Theresa SpergerInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.ORCID 0000-0002-3870-9870
Thomas ScattolinInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Guillaume MagninInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.ORCID 0000-0002-4726-6899
Franziska SchoenebeckInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.ORCID 0000-0003-0047-0929

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Disclosed herein is the first general chemo- and site-selective alkylation of C-Br bonds in the presence of COTf, C-Cl and other potentially reactive functional groups, using the air-, moisture-, and thermally stable dinuclear Pd

Indexed as

chemoselectivityCsp2-Csp3 couplingdimershomogeneous catalysispalladium

Identifiers

PMID28508520
PMCPMC5488304

What OpenQuestion holds

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LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.