Evidence map›Paper›PMID 28507688›Full record

ArticleChemical science2017

Donor-acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy.

Sachin R Chaudhari, John M Griffin, Katharina Broch, Anne Lesage, Vincent Lemaur, Dmytro Dudenko, Yoann Olivier, Henning Sirringhaus, Lyndon Emsley, Clare P Grey

Abstract read
In one paragraph

Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Chain Conformation and Exciton Delocalization in a Push-Pull Conjugated Polymer.Chemistry of materials : a publication of the American Chemical Society · 2023
    Article
  6. Review
  7. Article
  8. Tuning the Molecular Packing of Self-Assembled Amphiphilic PtChemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  9. Article
  10. Parametrizing the Spatial Dependence ofInternational journal of molecular sciences · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Sachin R ChaudhariInstitut des Sciences Analytiques , Centre de RMN à Très Hauts Champs , Université de Lyon (CNRS/ENS Lyon/UCB Lyon 1) , 69100 Villeurbanne , France.
John M GriffinDepartment of Chemistry , Lancaster University , Lancaster LA1 4YB , UK . Email: j.griffin@lancaster.ac.uk.ORCID 0000-0002-8943-3835
Katharina BrochOptoelectronics Group , Cavendish Laboratory , University of Cambridge , JJ Thomson Avenue , Cambridge CB3 0HE , UK.
Anne LesageInstitut des Sciences Analytiques , Centre de RMN à Très Hauts Champs , Université de Lyon (CNRS/ENS Lyon/UCB Lyon 1) , 69100 Villeurbanne , France.
Vincent LemaurLaboratory for Chemistry of Novel Materials , Center for Innovation and Research in Materials and Polymers (CIRMAP) , Université de Mons (UMons) , 20 Place du Parc , 7000 Mons , Belgium.
Dmytro DudenkoLaboratory for Chemistry of Novel Materials , Center for Innovation and Research in Materials and Polymers (CIRMAP) , Université de Mons (UMons) , 20 Place du Parc , 7000 Mons , Belgium.
Yoann OlivierLaboratory for Chemistry of Novel Materials , Center for Innovation and Research in Materials and Polymers (CIRMAP) , Université de Mons (UMons) , 20 Place du Parc , 7000 Mons , Belgium.ORCID 0000-0003-2193-1536
Henning SirringhausOptoelectronics Group , Cavendish Laboratory , University of Cambridge , JJ Thomson Avenue , Cambridge CB3 0HE , UK.
Lyndon EmsleyInstitut des Sciences et Ingénierie Chimiques , Ecole Polytechnique Fédérale de Lausanne (EPFL) , CH-1015 Lausanne , Switzerland.
Clare P GreyDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , UK.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Conjugated polymers show promising properties as cheap, sustainable and solution-processable semiconductors. A key challenge in the development of these materials is to determine the polymer chain structure, conformation and packing in both the bulk polymer and in thin films typically used in devices. However, many characterisation techniques are unable to provide atomic-level structural information owing to the presence of disorder. Here, we use molecular modelling, magic-angle spinning (MAS) and dynamic nuclear polarisation surface-enhanced NMR spectroscopy (DNP SENS) to characterise the polymer backbone group conformations and packing arrangement in the high-mobility donor-acceptor copolymer diketopyrrolo-pyrrole-dithienylthieno[3,2-

Identifiers

PMID28507688
PMCPMC5413886

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.