ArticleChemical science2017
Coevolution and ratiometric behaviour in metal cation-driven dynamic covalent systems.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Dynamic covalent self-assembly and self-sorting processes in the formation of imine-based macrocycles and macrobicyclic cages.Chemical science · 2023Article
- Imine- and Amine-Type Macrocycles Derived from Chiral Diamines and Aromatic Dialdehydes.Molecules (Basel, Switzerland) · 2022Review
- Spatiotemporal dynamics of self-assembled structures in enzymatically induced agonistic and antagonistic conditions.Chemical science · 2021Article
- Phase transfer of metal cations by induced dynamic carrier agents: biphasic extraction based on dynamic covalent chemistry.Chemical science · 2020Article
- Kinetic and Thermodynamic Modulation of Dynamic Imine Libraries Driven by the Hexameric Resorcinarene Capsule.Journal of the American Chemical Society · 2020Article
- Triple Self-Sorting in Constitutional Dynamic Networks: Parallel Generation of Imine-Based CuAngewandte Chemie (International ed. in English) · 2020Article
- Self-sorting of two imine-based metal complexes: balancing kinetics and thermodynamics in constitutional dynamic networks.Chemical science · 2019Article
- Multiple adaptation of constitutional dynamic networks and information storage in constitutional distributions of acylhydrazones.Chemical science · 2019Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Dynamic Covalent Libraries (DCLs) have been used to demonstrate coevolution behaviour on a molecular level using dynamic covalent molecules such as imines and hydrazones. Two systems are presented: the first system is based on a dialdehyde and two diamines in combination with Zn(ii) and Hg(ii) to form a 2 × 2 Constitutional Dynamic Network (CDN) of four complexes of macrocyclic bis-imines. Whereas the two metal ions, when reacted separately form a complex with each macrocycle with low selectivity, when applied together, each cation yields selectively a complex with one of the two macrocycles. Thus, the simultaneous application of both cations, where one might have expected the formation of four different complexes, results in the synergistic evolution (co-evolution) towards a simpler, more selective outcome under agonist amplification. The second system of 4 components, 2 amines and 2 aldehydes displays metalloselection together with a correlated evolution in distribution on complexation of Zn(ii) and Cu(i) with the dynamic ligand constituents and exhibits a dynamic ratiometry process related to the antagonistic behaviour of a pair of ligand constituents.
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Registered trials
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