ReviewMolecules (Basel, Switzerland)2017
Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.
Review in Molecules (Basel, Switzerland), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
18 citing papers in PubMed.
- Article
- Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.Chemical reviews · 2024Review
- Nickel binding enables isolation and reactivity of previously inaccessible 7-aza-2,3-indolynes.Science (New York, N.Y.) · 2024Article
- A decade of lessons in the activation of ArILChemical science · 2024Review
- Diaryl hypervalent bromines and chlorines: synthesis, structures and reactivities.Chemical science · 2024Review
- Selective multi-electron aggregation at a hypervalent iodine center by sequential disproportionation.Chemical communications (Cambridge, England) · 2023Article
- Synthesis and Structural Verification of an ArI(OTf)Angewandte Chemie (International ed. in English) · 2022Article
- Iodine-Iodine Cooperation Enables Metal-Free C-N Bond-Forming Electrocatalysis via Isolable Iodanyl Radicals.Journal of the American Chemical Society · 2022Article
- Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents.Molecules (Basel, Switzerland) · 2022Review
- Non-Palladium-Catalyzed Oxidative Coupling Reactions Using Hypervalent Iodine Reagents.Frontiers in chemistry · 2022Review
- The role of hypervalent iodine(iii) reagents in promoting alkoxylation of unactivated C(spChemical science · 2021Article
- Heterocyclic group transfer reactions with I(iii)Chemical science · 2021Article
- Halogen Complexes of Anionic N-Heterocyclic Carbenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Hypervalent Iodine Reagents in Palladium-Catalyzed Oxidative Cross-Coupling Reactions.Frontiers in chemistry · 2020Review
- Aerobic C-C and C-O bond formation reactions mediated by high-valent nickel species.Chemical science · 2019Article
- Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives.Chemical communications (Cambridge, England) · 2019Article
- (Poly)cationic λEuropean journal of organic chemistry · 2018Article
- Atom-economical group-transfer reactions with hypervalent iodine compounds.Beilstein journal of organic chemistry · 2018Review
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Over the last 20 years, high valent metal complexes have evolved from mere curiosities to being at the forefront of modern catalytic method development. This approach has enabled transformations complimentary to those possible via traditional manifolds, most prominently carbon-heteroatom bond formation. Key to the advancement of this chemistry has been the identification of oxidants that are capable of accessing these high oxidation state complexes. The oxidant has to be both powerful enough to achieve the desired oxidation as well as provide heteroatom ligands for transfer to the metal center; these heteroatoms are often subsequently transferred to the substrate via reductive elimination. Herein we will review the central role that hypervalent iodine reagents have played in this aspect, providing an ideal balance of versatile reactivity, heteroatom ligands, and mild reaction conditions. Furthermore, these reagents are environmentally benign, non-toxic, and relatively inexpensive compared to other inorganic oxidants. We will cover advancements in both catalysis and high valent complex isolation with a key focus on the subtle effects that oxidant choice can have on reaction outcome, as well as limitations of current reagents.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.