ReviewProceedings. Mathematical, physical, and engineering sciences2017
Some aspects of radical cascade and relay reactions.
Review in Proceedings. Mathematical, physical, and engineering sciences, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Cathodic electroorganic reaction on silicon oxide dielectric electrode.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Intra- and intermolecular Fe-catalyzed dicarbofunctionalization of vinyl cyclopropanes.Chemical science · 2020Article
- Synthetic and Computational Study of Tin-Free Reductive Tandem Cyclizations of Neutral Aminyl Radicals.Organic letters · 2018Article
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Authors and funding
2 authors.
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Abstract
The ability to create carbon-carbon bonds is at the heart of organic synthesis. Radical processes are particularly apt at creating such bonds, especially in cascade or relay sequences where more than one bond is formed, allowing for a rapid assembly of complex structures. In the present brief overview, examples taken from the authors' laboratory will serve to illustrate the strategic impact of radical-based approaches on synthetic planning. Transformations involving nitrogen-centred radicals, electron transfer from metallic nickel and the reversible degenerative exchange of xanthates will be presented and discussed. The last method has proved to be a particularly powerful tool for the
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