Evidence map›Paper›PMID 28477137›Full record

ArticleJournal of fluorescence2017

Substituent Dependence Charge Transfer and Photochemical Properties of Donor-Acceptor Substituted Ethenyl Thiophenes.

Naresh Kumar, Jagdeep Kumar, Prasanta Kumar Hota

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Article in Journal of fluorescence, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Naresh KumarDepartment of Chemistry, School of Sciences, Hemvati Nandan Bahuguna Garhwal University, Srinagar Garhwal, Pauri Garhwal, Uttarakhand, 246174, India.
Jagdeep KumarDepartment of Chemistry, School of Sciences, Hemvati Nandan Bahuguna Garhwal University, Srinagar Garhwal, Pauri Garhwal, Uttarakhand, 246174, India.
Prasanta Kumar HotaDepartment of Chemistry, School of Sciences, Hemvati Nandan Bahuguna Garhwal University, Srinagar Garhwal, Pauri Garhwal, Uttarakhand, 246174, India. p.hota@hnbgu.ac.in.

Funding

University Grants Commission F.30-62/2014(BSR)
6 · The paper itself

Abstract

Donor-acceptor conjugated molecules with efficient light induced properties represent interesting material for electronic device application. In this context, we have calculated excited state dipole moment of three ethenyl thiophenes (1-3) bearing varied electron donor-acceptor substituent in p-phenyl unit using Lippert-Mataga, Bakhshiev and Kawski method. It is found that 1 with strong electron-withdrawing nitro substituent, is exhibiting charge transfer and highly dipolar excited state as compared to 2 and 3. Photochemical studies of 1-3, indicate towards the charge transfer dependence trans-cis photoisomerization under direct irradiation condition. Compound 1 exhibits charge transfer and less efficient towards photoisomerization, whereas 2 and 3 undergo efficient photoisomerization. Graphical Abstract Substituent dependence charge transfer and photochemical properties of donor-acceptor substituted ethenyl thiophenes.

Indexed as

AbsorptionCharge transferDipole momentFluorescenceFluorescence quantum yieldPhotoisomerizationPhotoisomerization quantum yield

Identifiers

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.