ArticleChemical science2017
Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 32 citations in OpenAlex.
- Rapid Generation of Transition-State Conformer Ensembles via Constrained Distance Geometry.Journal of chemical information and modeling · 2026Article
- Evaluation of Tungsten Catalysis among Early Transition Metals forInorganic chemistry · 2024Article
- Reassessment of NChemical science · 2022Article
- Ti-Catalyzed and -Mediated Oxidative Amination Reactions.Accounts of chemical research · 2021Article
- Ti-catalyzed ring-opening oxidative amination of methylenecyclopropanes with diazenes.Chemical science · 2020Article
- Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules.Coordination chemistry reviews · 2020Article
- Study on the grain size control of metatitanic acid in a mixture acid system based on Arrhenius and Boltzmann fitting.RSC advances · 2020Article
- Carbodiimide Synthesis via Ti-Catalyzed Nitrene Transfer from Diazenes to Isocyanides.ACS catalysis · 2019Article
- Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles.Journal of the American Chemical Society · 2019Article
- Modern applications of low-valent early transition metals in synthesis and catalysis.Nature reviews. Chemistry · 2019Article
- Mechanism of Ti-Catalyzed Oxidative Nitrene Transfer in [2 + 2 + 1] Pyrrole Synthesis from Alkynes and Azobenzene.Journal of the American Chemical Society · 2018Article
- Titanium redox catalysis: insights and applications of an earth-abundant base metal.Dalton transactions (Cambridge, England : 2003) · 2017Article
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Early transition metals (TMs), such as titanium, generally resist undergoing reductive elimination to form C-X bonds due to their weak electronegativity. By analyzing the mechanism of the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes, the present study revealed that titanium is able to promote C-N bond formation
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Registered trials
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