ArticleChemical science2017
On thermodynamic inconsistencies in several photosynthetic and solar cell models and how to fix them.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- A Theoretical Perspective of the Photochemical Potential in the Spectral Performance of Photovoltaic Cells.Entropy (Basel, Switzerland) · 2021Article
- On the performance of a photosystem II reaction centre-based photocell.Chemical science · 2017Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We analyze standard theoretical models of solar energy conversion developed to study solar cells and photosynthetic systems. We show that assuming the energy transfer to the reaction center/electric circuit is through a decay rate or "sink", contradicts the second law of thermodynamics. We put forward a thermodynamically consistent alternative by explicitly considering parts of the reaction center/electric circuit and by employing a Hamiltonian transfer. The predicted energy transfer by the new scheme differs from the one found using a decay rate, casting doubts on the validity of the conclusions obtained by models which include the latter.
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Registered trials
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