ArticleChemical science2017
Dendritic polarizing agents for DNP SENS.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Toward Generalized Solution-StateThe journal of physical chemistry letters · 2025Article
- Cryogenic and Dissolution DNP NMR on γ-Irradiated Organic Molecules.Journal of the American Chemical Society · 2024Article
- Polarizing agents for efficient high field DNP solid-state NMR spectroscopy under magic-angle spinning: from design principles to formulation strategies.Chemical science · 2023Review
- Spin Hyperpolarization in Modern Magnetic Resonance.Chemical reviews · 2023Review
- Design Principles for the Development of Gd(III) Polarizing Agents for Magic Angle Spinning Dynamic Nuclear Polarization.The journal of physical chemistry. C, Nanomaterials and interfaces · 2022Article
- Small Molecules, Non-Covalent Interactions, and Confinement.Molecules (Basel, Switzerland) · 2020Review
- Predicting the DNP-SENS efficiency in reactive heterogeneous catalysts from hydrophilicity.Chemical science · 2018Article
Corrections and comments
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Authors and funding
16 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy (DNP SENS) is an effective method to significantly improve solid-state NMR investigation of solid surfaces. The presence of unpaired electrons (polarizing agents) is crucial for DNP, but it has drawbacks such as leading to faster nuclear spin relaxation, or even reaction with the substrate under investigation. The latter can be a particular problem for heterogeneous catalysts. Here, we present a series of carbosilane-based dendritic polarizing agents, in which the bulky dendrimer can reduce the interaction between the solid surface and the free radical. We thereby preserve long nuclear
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Registered trials
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