ArticleChemical science2016
Perylene bisimide hydrogels and lyotropic liquid crystals with temperature-responsive color change.
Article in Chemical science, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Multidirectionally Controlled Arrangement via Ion-Pairing Assembly of Amphiphilic Charged π-Electronic Systems.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- "Confined Eutectic" Strategy for Visual Refrigeration Responsive Fluorescent Materials with Easy Preparation and Multi-Color Tunability.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Synthesis and Optoelectronic Properties of Perylene Diimide-Based Liquid Crystals.Molecules (Basel, Switzerland) · 2025Review
- Visible-Light Driven Control Over Triply and Quadruply Hydrogen-Bonded Supramolecular Assemblies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Highly efficient and selective supramolecular hydrogel sensor based on rhodamine 6G derivatives.RSC advances · 2021Article
- Solvent-controlledChemical science · 2020Article
- Modulation of the Self-Assembly of π-Amphiphiles in Water from Enthalpy- to Entropy-Driven by Enwrapping Substituents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Rhodamine-immobilized optical hydrogels with shape deformation and HgScientific reports · 2020Article
- Organic Acid Regulated Self-Assembly and Photophysical Properties of Perylene Bisimide Derivatives.Materials (Basel, Switzerland) · 2020Article
- Thermodynamic insights into the entropically driven self-assembly of amphiphilic dyes in water.Chemical science · 2019Article
- Insights into the Kinetics of Supramolecular Comonomer Incorporation in Water.Macromolecules · 2019Article
- Hydrogen-bonded perylene bisimide J-aggregate aqua material.Chemical science · 2018Article
- Transforming aACS omega · 2018Article
- Relationship between Side-Chain Polarity and the Self-Assembly Characteristics of Perylene Diimide Derivatives in Aqueous Solution.ChemistryOpen · 2017Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The self-assembly of perylene bisimide (PBI) dyes bearing oligo ethylene glycol (OEG) units in water affords responsive functional nanostructures characterized by their lower critical solution temperature (LCST). Tuning of the LCST is realized by a supramolecular approach that relies on two structurally closely related PBI-OEG molecules. The two PBIs socially co-assemble in water and the resulting nanostructures exhibit a single LCST in between the transition temperatures of the aggregates formed by single components. This permits to precisely tune the transition from a hydrogel to a lyotropic liquid crystal state at temperatures between 26 and 51 °C by adjusting the molar fraction of the two PBIs. Owing to concomitant changes in PBI-PBI interactions this phase transition affords a pronounced color change with "fluorescence-on" response that can be utilized as a smart temperature sensory system.
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Registered trials
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