ArticleJournal of the American Chemical Society2017
Synthesis of Chiral Tertiary Boronic Esters: Phosphonate-Directed Catalytic Asymmetric Hydroboration of Trisubstituted Alkenes.
Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Copper-Catalyzed Asymmetric Hydroboration of Alkynes to C-N Axially Chiral Azaborines via Dynamic Kinetic Resolution.Angewandte Chemie (International ed. in English) · 2026Article
- Copper-catalysed asymmetric hydroboration of alkenes with 1,2-benzazaborines to access chiral naphthalene isosteres.Nature chemistry · 2024Article
- Asymmetric synthesis of flavanols via Cu-catalyzed kinetic resolution of chromenes and their anti-inflammatory activity.Science advances · 2022Article
- Bakuchiol - a natural meroterpenoid: structure, isolation, synthesis and functionalization approaches.RSC advances · 2022Review
- Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration.Nature communications · 2021Article
- Ligand Conformational Flexibility Enables Enantioselective Tertiary C-B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration.Journal of the American Chemical Society · 2021Article
- Rhodium-catalysed selective C-C bond activation and borylation of cyclopropanes.Chemical science · 2021Article
- Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications.Chemical science · 2020Article
- Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions.Angewandte Chemie (International ed. in English) · 2019Article
- Ligand-Controlled Regiodivergent Enantioselective Rhodium-Catalyzed Alkene Hydroboration.Angewandte Chemie (International ed. in English) · 2019Article
- Facile access to functionalized chiral secondary benzylic boronic estersChemical science · 2019Article
- Phosphonate-Directed Catalytic Asymmetric Hydroboration: Delivery of Boron to the More Substituted Carbon, Leading to Chiral Tertiary Benzylic Boronic Esters.ACS catalysis · 2018Article
- Enantioselective Construction of Tertiary Boronic Esters by Conjunctive Cross-Coupling.Angewandte Chemie (International ed. in English) · 2018Article
- Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids.Chemical science · 2018Article
- Rhodium-catalyzed asymmetric hydroboration of γ,δ-unsaturated amide derivatives: δ-borylated amides.Chemical communications (Cambridge, England) · 2018Article
- Heck Reaction of Electronically Diverse Tertiary Alkyl Halides.Organic letters · 2018Article
- Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes.Journal of the American Chemical Society · 2017Article
Corrections and comments
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2 authors.
Funding
Abstract
Highly enantioselective rhodium-catalyzed hydroboration of allylic phosphonates by pinacolborane affords chiral tertiary boronic esters. The β-borylated phosphonates are readily converted to chiral β- and γ-hydroxyphosphonates and aminophosphonates and to phosphonates bearing a quaternary carbon stereocenter. The utility of the latter is illustrated by the synthesis of (S)-(+)-bakuchiol methyl ether.
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