ArticleChemistry of materials : a publication of the American Chemical Society2017
Missing Linkers: An Alternative Pathway to UiO-66 Electronic Structure Engineering.
Article in Chemistry of materials : a publication of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
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Who cites it
35 citing papers in PubMed.
- Which modification for which feedstock? a strategy-by-strategy review of Zr-MOF catalysts for biodiesel production.RSC advances · 2026Review
- Defect-Regulated Hetero-Trimetallic Nanocatalysts Augment Sonocatalytic Dynamic Therapy by Charge Transfer Facilitation and Ferroptosis Cascade Induction.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Zr-based metal-organic frameworks for colorimetric sensing applications.RSC applied interfaces · 2026Review
- Quasi-MOFs in water treatment: Synthesis, characterization, and applications.Environmental science and ecotechnology · 2026Review
- Computational Modeling of Reticular Materials: The Past, the Present, and the Future.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Accelerated Photogenerated Charge Separation Driven Synergistically by the Interfacial Electric Field and Work Function in Z-Scheme Zn-NiExploration (Beijing, China) · 2025Article
- Switching-Off to Switching-On Triplet Formation Through Singlet-Triplet Intersystem Crossing in Porphyrin Metal-Organic Frameworks.Angewandte Chemie (International ed. in English) · 2025Article
- Beyond Solution Chemistry: Mechanochemistry Enables Clustered Defects in Metal-Organic Frameworks.Inorganic chemistry · 2025Article
- Pressure Sensitivity of UiO-66 Framework with Encapsulated Spin Probe: A Molecular Dynamics Study.Molecules (Basel, Switzerland) · 2025Article
- Reductive Photocatalytic Proton-Coupled Electron Transfer by a Zirconium-Based Molecular Platform.Angewandte Chemie (International ed. in English) · 2024Article
- Promoting photoswitching in mismatching mixed-linker multivariate ZrRSC advances · 2024Article
- Highly Dispersive Gold Nanoclusters Confined within Micropores of Defective UiO-66 for Highly Efficient Aldehyde Oxidation at Mild Conditions.International journal of molecular sciences · 2024Article
- Defect Engineering Strategy for Superior Integration of Metal-Organic Framework and Halide Perovskite as a Fluorescence Sensing Material.ACS applied materials & interfaces · 2024Article
- Exploring Defect-Engineered Metal-Organic Frameworks with 1,2,4-Triazolyl Isophthalate and Benzoate Linkers.Inorganic chemistry · 2024Article
- Microporous Zr-metal-organic frameworks based-nanocomposites for thermoelectric applications.Scientific reports · 2024Article
- Synthetic control of correlated disorder in UiO-66 frameworks.Nature communications · 2023Article
- Challenges in modelling dynamic processes in realistic nanostructured materials at operating conditions.Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2023Review
- Fundamental Perspectives on the Electrochemical Water Applications of Metal-Organic Frameworks.Nano-micro letters · 2023Review
- Metal-Organic Frameworks as Photocatalysts for Solar-Driven Overall Water Splitting.Chemical reviews · 2023Review
- Tuning the Photocatalytic Activity of Ti-Based Metal-Organic Frameworks through Modulator Defect-Engineered Functionalization.ACS applied materials & interfaces · 2022Article
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Authors and funding
5 authors.
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Abstract
UiO-66 is a promising metal-organic framework for photocatalytic applications. However, the ligand-to-metal charge transfer of an excited electron is inefficient in the pristine material. Herein, we assess the influence of missing linker defects on the electronic structure of UiO-66 and discuss their ability to improve ligand-to-metal charge transfer. Using a new defect classification system, which is transparent and easily extendable, we identify the most promising photocatalysts by considering both relative stability and electronic structure. We find that the properties of UiO-66 defect structures largely depend on the coordination of the constituent nodes and that the nodes with the strongest local distortions alter the electronic structure most. Defects hence provide an alternative pathway to tune UiO-66 for photocatalytic purposes, besides linker modification and node metal substitution. In addition, the decomposition of MOF properties into node- and linker-based behavior is more generally valid, so we propose orthogonal electronic structure tuning as a paradigm in MOF design.
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