ArticleACS catalysis2017
Mild, Redox-Neutral Alkylation of Imines Enabled by an Organic Photocatalyst.
Article in ACS catalysis, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.
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Who cites it
33 citing papers in PubMed.
- A Dual Photoredox/Cobalt Catalytic System Enables Markovnikov-Selective Hydroaminoalkylation of Alkenes.Precision chemistry · 2026Article
- Photocatalytic coupling of phenols with iminesOrganic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Heterogeneous photocatalytic aldehyde alkylative amination for multicomponent synthesis of α-branched amines.National science review · 2026Article
- Visible-Light-Driven Benzylation ofACS catalysis · 2026Article
- Nucleophilic Additions of Organolithium Reagents to Heterocyclic Aldimines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2025Article
- Enhancing Electron Donor-Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Photocatalytic Decarboxylative Alkylation of Cyclic Imine-BFJournal of the American Chemical Society · 2024Article
- Recent advances in combining photo- and N-heterocyclic carbene catalysis.Chemical science · 2023Review
- Direct allylic acylation via cross-coupling involving cooperative N‑heterocyclic carbene, hydrogen atom transfer, and photoredox catalysis.Nature communications · 2023Article
- Eco-friendly and efficient catalyst-free synthesis ofRSC advances · 2023Article
- Excited-state palladium-catalysed reductive alkylation of imines: scope and mechanism.Chemical science · 2022Article
- First Evidence of Tris(catecholato)silicate Formation from Hydrolysis of an Alkyl Bis(catecholato)silicate.Molecules (Basel, Switzerland) · 2022Article
- Photoredox-Catalyzed Oxidation of Anions for the Atom-Economical Hydro-, Amido-, and Dialkylation of Alkenes.The Journal of organic chemistry · 2022Article
- Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.Chemical reviews · 2022Review
- Stereoselective synthesis of unnatural α-amino acid derivatives through photoredox catalysis.Chemical science · 2021Article
- Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy.Chemical reviews · 2020Article
- Allylic C(spChemical science · 2020Article
- Radical-Polar Crossover Annulation: A Platform for Accessing Polycyclic Cyclopropanes.Advanced synthesis & catalysis · 2020Article
- Cascade Cross-Coupling of Dienes: Photoredox and Nickel Dual Catalysis.Angewandte Chemie (International ed. in English) · 2020Article
- Distinctive reactivity ofBeilstein journal of organic chemistry · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
An operationally simple, mild, redox-neutral method for the photoredox alkylation of imines is reported. Utilizing an inexpensive organic photoredox catalyst, alkyl radicals are readily generated from the single-electron oxidation of ammonium alkyl bis(catecholato)silicates and are subsequently engaged in a C-C bond-forming reaction with imines. The process is highly selective, metal-free, and does not require a large excess of the alkylating reagent or the use of acidic additives.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.