ReviewEuropean journal of organic chemistry2017
Metal-Catalysed Azidation of Organic Molecules.
Review in European journal of organic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Iron-catalyzed three-component 1,2-azidoalkylation of conjugated dienesChemical science · 2025Article
- Simple, catalytic C(spChemical communications (Cambridge, England) · 2024Article
- Tetrabutylammonium iodide-catalyzed oxidative α-azidation of β-ketocarbonyl compounds using sodium azide.Beilstein journal of organic chemistry · 2024Article
- Iron-Mediated Photochemical Anti-Markovnikov Hydroazidation of Unactivated Olefins.Journal of the American Chemical Society · 2023Article
- Azido-alkynylation of alkenes through radical-polar crossover.Chemical science · 2023Article
- Decatungstate-photocatalysed C(spChemical communications (Cambridge, England) · 2022Article
- N-Terminal Selective C-H Azidation of Proline-Containing Peptides: a Platform for Late-Stage Diversification.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Copper-Catalyzed Azide-Alkyne Cycloaddition of Hydrazoic Acid FormedThe Journal of organic chemistry · 2022Article
- Selective Azidooxygenation of Alkenes Enabled by Photo-induced Radical Transfer Using Aryl-λACS omega · 2021Article
- Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C(Journal of the American Chemical Society · 2021Article
- Mangana(iii/iv)electro-catalyzed C(spChemical science · 2020Article
- Site-Selective Copper-Catalyzed Azidation of Benzylic C-H Bonds.Journal of the American Chemical Society · 2020Article
- (Salen)Mn(iii)-catalyzed chemoselective acylazidation of olefins.Chemical science · 2018Article
- Towards an Asymmetric Organocatalytic α-Azidation of β-Ketoesters.Molecules (Basel, Switzerland) · 2018Article
- Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles.Journal of the American Chemical Society · 2017Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The azide moiety is a desirable functionality in organic molecules, useful in a variety of transformations such as olefin aziridination, C-H bond amination, isocyanate synthesis, the Staudinger reaction and the formation of azo compounds. To harness the versatility of the azide functionality fully it is important that these compounds be easy to prepare, in a clean and cost-effective manner. Conventional (non-catalysed) methods to synthesise azides generally require quite harsh reaction conditions that are often not tolerant of functional groups. In the last decade, several metal-catalysed azidations have been developed in attempts to circumvent this problem. These methods are generally faster, cleaner and more functional-group-tolerant than conventional methods to prepare azides, and can sometimes even be conveniently combined with one-pot follow-up transformations of the installed azide moiety. This review highlights metal-catalysed approaches to azide synthesis, with a focus on the substrate scopes and mechanisms, as well as on advantages and disadvantages of the methods. Overall, metal-catalysed azidation reactions provide shorter routes to a variety of potentially useful organic molecules containing the azide moiety.
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Registered trials
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