ArticleAngewandte Chemie (International ed. in English)2017
Hierarchical Corannulene-Based Materials: Energy Transfer and Solid-State Photophysics.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Charge-transfer dynamics in bowl-shaped imide-functionalized corannulenes at ensemble and single-molecule levels.Chemical science · 2026Article
- Make it Double: [4]Cumulene Thermal Core Transformation and Chemical Reduction.Organic letters · 2025Article
- Room-Temperature Multiple Phosphorescence from Functionalized Corannulenes: Temperature Sensing and Afterglow Organic Light-Emitting Diode.Angewandte Chemie (International ed. in English) · 2023Article
- Connecting the dots for fundamental understanding of structure-photophysics-property relationships of COFs, MOFs, and perovskites using a Multiparticle Holstein Formalism.Chemical science · 2023Review
- Synthesis of azahelicenes through Mallory reaction of imine precursors: corannulene substrates provide an exception to the rule in oxidative photocyclizations of diarylethenes.Chemical science · 2021Article
- Hierarchical Corannulene-Based Materials: Energy Transfer and Solid-State Photophysics.Angewandte Chemie (International ed. in English) · 2017Article
Corrections and comments
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Authors and funding
11 authors.
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Abstract
We report the first example of a donor-acceptor corannulene-containing hybrid material with rapid ligand-to-ligand energy transfer (ET). Additionally, we provide the first time-resolved photoluminescence (PL) data for any corannulene-based compounds in the solid state. Comprehensive analysis of PL data in combination with theoretical calculations of donor-acceptor exciton coupling was employed to estimate ET rate and efficiency in the prepared material. The ligand-to-ligand ET rate calculated using two models is comparable with that observed in fullerene-containing materials, which are generally considered for molecular electronics development. Thus, the presented studies not only demonstrate the possibility of merging the intrinsic properties of π-bowls, specifically corannulene derivatives, with the versatility of crystalline hybrid scaffolds, but could also foreshadow the engineering of a novel class of hierarchical corannulene-based hybrid materials for optoelectronic devices.
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Registered trials
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