ArticleNature communications2017
Constructive quantum interference in a bis-copper six-porphyrin nanoring.
Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
11 citing papers in PubMed.
- π-Conjugation Mediates Competing J12 and J13 Interactions at the Nanometric Scale in Linear Fe(III) Porphyrin Trimers.Inorganic chemistry · 2026Article
- RIDME Spectroscopy: New Topics Beyond the Determination of Electron Spin-Spin Distances.The journal of physical chemistry letters · 2025Review
- Theoretical and modelling investigation of pendant groups effect on quantum interference for single-molecule junctions.RSC advances · 2024Article
- Carbon Nanohoops: Multiple Molecular Templates for Exploring Spectroscopic, Electronic, and Thermoelectric Properties.ACS omega · 2024Article
- Title: experimental realisation of multi-qubit gates using electron paramagnetic resonance.Nature communications · 2023Article
- Synthesis of mono-nitroxides and of bis-nitroxides with varying electronic through-bond communication.Organic & biomolecular chemistry · 2023Article
- Accessing the triplet state of perylenediimide by radical-enhanced intersystem crossing.Chemical science · 2022Article
- A Comparison of Cysteine-Conjugated Nitroxide Spin Labels for Pulse Dipolar EPR Spectroscopy.Molecules (Basel, Switzerland) · 2021Article
- Soft chromophore featured liquid porphyrins and their utilization toward liquid electret applications.Nature communications · 2019Article
- Deep neural network processing of DEER data.Science advances · 2018Article
- Unexpected Interactions between Alkyl Straps and Pyridine Ligands in Sulfur-Strapped Porphyrin Nanorings.The Journal of organic chemistry · 2017Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The exchange interaction, J, between two spin centres is a convenient measure of through bond electronic communication. Here, we investigate quantum interference phenomena in a bis-copper six-porphyrin nanoring by electron paramagnetic resonance spectroscopy via measurement of the exchange coupling between the copper centres. Using an analytical expression accounting for both dipolar and exchange coupling to simulate the time traces obtained in a double electron electron resonance experiment, we demonstrate that J can be quantified to high precision even in the presence of significant through-space coupling. We show that the exchange coupling between two spin centres is increased by a factor of 4.5 in the ring structure with two parallel coupling paths as compared to an otherwise identical system with just one coupling path, which is a clear signature of constructive quantum interference.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.