Evidence map›Paper›PMID 28286695›Full record

ArticleACS catalysis2017

When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides.

Indrek Kalvet, Qianqian Guo, Graham J Tizzard, Franziska Schoenebeck

Abstract read
In one paragraph

Article in ACS catalysis, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.

0numbers the graph read from it
0cells of the map it votes in
25citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

25 citing papers in PubMed.

  1. Article
  2. Article
  3. Discovery of NiJournal of the American Chemical Society · 2025
    Article
  4. Article
  5. Article
  6. A Neutral PCThe Journal of organic chemistry · 2024
    Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Metal-Free Trifluoromethylthiolation of Arylazo Sulfones.The Journal of organic chemistry · 2021
    Article
  15. Dialkyl Ether Formation at High-Valent Nickel.Journal of the American Chemical Society · 2020
    Article
  16. Article
  17. A Simple Nickel Catalyst Enabling an E-Selective Alkyne Semihydrogenation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
  18. Article
  19. Nickel-Catalyzed Conversion of Enol Triflates into Alkenyl Halides.Angewandte Chemie (International ed. in English) · 2019
    Article
  20. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Indrek KalvetInstitute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, 52074 Aachen, Germany.
Qianqian GuoInstitute of Inorganic Chemistry, X-ray Crystallography, RWTH Aachen University , Landoltweg 1, 52074 Aachen, Germany.
Graham J TizzardEPSRC National Crystallography Service, School of Chemistry, University of Southampton , University Road, SO17 1BJ Southampton, United Kingdom.
Franziska SchoenebeckInstitute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, 52074 Aachen, Germany.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The direct introduction of the valuable SCF

Indexed as

cross-couplingDFTfluorineligandmechanismsnickel

Identifiers

PMID28286695
PMCPMC5339856

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.