ArticleScientific reports2017
Spatial control of chirality in supramolecular aggregates.
Article in Scientific reports, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Kinetic Investigations on the Chiral Induction by Amino Acids in Porphyrin J-Aggregates.International journal of molecular sciences · 2023Article
- Racemization in Post-Translational Modifications Relevance to Protein Aging, Aggregation and Neurodegeneration: Tip of the Iceberg.Symmetry · 2021Article
- Effects of the Mixing Protocol on the Self-Assembling Process of Water Soluble Porphyrins.International journal of molecular sciences · 2021Article
- Tunable Supramolecular Chirogenesis in the Self-Assembling of Amphiphilic Porphyrin Triggered by Chiral Amines.International journal of molecular sciences · 2020Article
- Influence of Magnetic Micelles on Assembly and Deposition of Porphyrin J-Aggregates.Nanomaterials (Basel, Switzerland) · 2020Article
- The Assembly of Porphyrin Systems in Well-Defined Nanostructures: An Update.Molecules (Basel, Switzerland) · 2019Review
- Nanohybrid Assemblies of Porphyrin and AuNanomaterials (Basel, Switzerland) · 2019Article
- Giant intrinsic circular dichroism of prolinol-derived squaraine thin films.Nature communications · 2018Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chirality is one of the most intriguing properties of matter related to a molecule's lack of mirror symmetry. The transmission of chirality from the molecular level up to the macroscopic scale has major implications in life sciences but it is also relevant for many chemical applications ranging from catalysis to spintronic. These technological applications require an accurate control of morphology, homogeneity and chiral handedness of thin films and nanostructures. We demonstrate a simple approach to specifically transfer chirality to the model supramolecular system of J aggregates of the protonated form of tetrakis(4-sulfonatophenyl)-porphyrin by utilizing a soft lithography technique. This approach successfully allows the fabrication of an ordered distribution of sub-micrometric structures in precise and controllable positions with programmed chirality, providing a fundamental breakthrough toward the exploitation of chiral supramolecular aggregates in technological applications, such as sensors, non-linear optics and spintronic.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.