ArticleScientific reports2017
Controlling self-assembly of diphenylalanine peptides at high pH using heterocyclic capping groups.
Article in Scientific reports, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Self-sorting and co-assembly control in multicomponent supramolecular hydrogels with dual monomer and polymer statistical distribution.Communications chemistry · 2025Article
- Advancing Synthetic Hydrogels through Nature-Inspired Materials Chemistry.Advanced materials (Deerfield Beach, Fla.) · 2024Review
- Atomic structures of naphthalene dipeptide micelles unravel mechanisms of assembly and gelation.Cell reports. Physical science · 2024Article
- Applications of microscopy and small angle scattering techniques for the characterisation of supramolecular gels.Beilstein journal of organic chemistry · 2024Review
- Self-Assembly of Unprotected Dipeptides into Hydrogels: Water-Channels Make the Difference.Chembiochem : a European journal of chemical biology · 2022Article
- Using chirality to influence supramolecular gelation.Chemical science · 2019Article
- Protein-induced low molecular weight hydrogelator self-assembly through a self-sustaining process.Chemical science · 2019Article
- Hierarchically Compartmentalized Supramolecular Gels through Multilevel Self-Sorting.Journal of the American Chemical Society · 2019Article
- Drying Affects the Fiber Network in Low Molecular Weight Hydrogels.Biomacromolecules · 2017Article
- Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels.Scientific reports · 2017Article
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Using small angle neutron scattering (SANS), it is shown that the existence of pre-assembled structures at high pH for a capped diphenylalanine hydrogel is controlled by the selection of N-terminal heterocyclic capping group, namely indole or carbazole. At high pH, changing from a somewhat hydrophilic indole capping group to a more hydrophobic carbazole capping group results in a shift from a high proportion of monomers to self-assembled fibers or wormlike micelles. The presence of these different self-assembled structures at high pH is confirmed through NMR and circular dichroism spectroscopy, scanning probe microscopy and cryogenic transmission electron microscopy.
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