ArticleJournal of the American Chemical Society2017
Stereocontrolled Synthesis of Kalihinol C.
Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Unified Synthesis of 2-Isocyanoallopupukeanane and 9-Isocyanopupukeanane through a "Contra-biosynthetic" Rearrangement.Angewandte Chemie (International ed. in English) · 2024Article
- An Enantiospecific Synthesis of Isoneoamphilectane Confirms Its Strained Tricyclic Structure.Journal of the American Chemical Society · 2023Article
- Nucleophilic Isocyanation.ACS omega · 2020Review
- Development of a Strategy for Linear-Selective Cu-Catalyzed Reductive Coupling of Ketones and Allenes for the Synthesis of Chiral γ-Hydroxyaldehyde Equivalents.Organic letters · 2019Article
- The High Chemofidelity of Metal-Catalyzed Hydrogen Atom Transfer.Accounts of chemical research · 2018Article
- Diverse secondary C(spChemical science · 2018Article
- Scalable synthesis of enaminones utilizing Gold's reagents.Tetrahedron, asymmetry · 2017Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
We report a concise chemical synthesis of kalihinol C via a possible biosynthetic intermediate, "protokalihinol", which was targeted as a scaffold en route to antiplasmodial analogs. High stereocontrol of the kalihinol framework relies on a heterodendralene cascade to establish the target stereotetrad. Common problems of regio- and chemoselectivity encountered in the kalihinol class are explained and solved.
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Registered trials
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