ArticleInorganic chemistry2017
Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties.
Article in Inorganic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
13 citing papers in PubMed.
- Isolable C-Phosphonio-Boratavinyl Anion.Angewandte Chemie (International ed. in English) · 2026Article
- Investigating Metal-Metal Bond Polarization in a Heteroleptic Tris-Ylide Diiron System.Inorganic chemistry · 2023Article
- New Insight into the Reactivity of S,S-Bis-ylide.Molecules (Basel, Switzerland) · 2023Article
- Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PCChemical science · 2023Article
- Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl- and Amino-Substituted Metallated Ylide.ChemistryOpen · 2021Article
- A 2,2'-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenesChemical science · 2021Article
- Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and COrganometallics · 2020Article
- Synthesis of Low-Valent Dinuclear Group 14 Compounds with Element-Element Bonds by Transylidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Synthesis, Isolation and Crystal Structures of the Metalated Ylides [CyZeitschrift fur anorganische und allgemeine Chemie · 2020Article
- Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment.Angewandte Chemie (International ed. in English) · 2019Article
- Ylide-Functionalization via Metalated Ylides: Synthesis and Structural Properties.ChemistryOpen · 2019Article
- Isolation of the Metalated Ylides [PhChemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis.Angewandte Chemie (International ed. in English) · 2018Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The development and design of new ligand systems with special donor properties has been essential for crucial advances made in main-group-element and transition-metal chemistry over the years. This Forum Article focuses on metalated ylides as novel ligand systems. These anionic congeners of bisylides possess likewise two lone pairs of electrons at the central carbon atom and can thus function as X,L-type ligands with strong donor abilities. This article highlights recent efforts in the isolation and application of metalated ylides with a focus on work from this laboratory. We summarize structural and electronic properties and their use in organic synthesis as well as main-group-element and transition-metal chemistry.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.