ArticleComments on modern chemistry. Part A, Comments on inorganic chemistry : a journal of critical discussion of the current literature2016
Experimental and Theoretical Aspects of Anion Complexes with a Thiophene-Based Cryptand.
Article in Comments on modern chemistry. Part A, Comments on inorganic chemistry : a journal of critical discussion of the current literature, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed, 6 citations in OpenAlex.
- An IdealACS omega · 2017Article
- Remarkable hexafunctional anion receptor with operational urea-based inner cleft and thiourea-based outer cleft: Novel design with high-efficiency for sulfate binding.Scientific reports · 2017Article
- Synthetic Receptors Induce Anti Angiogenic and Stress Signaling on Human First Trimester Cytotrophoblast Cells.International journal of environmental research and public health · 2017Article
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6 authors at 1 institution in 1 country.
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Abstract
Selective recognition of anions has received a tremendous attention in recent years because of their significant importance in biology and environment. This article highlights our recent research on a thiophene-based azacryptand that has been shown to effectively bind anions including iodide, bromide, chloride, nitrate and sulfate. Structural studies indicate that the ligand forms inclusion complexes with chloride and iodide. On the other hand, it forms cleft-like complexes with nitrate and sulfate, where three anions are bound between the cyclic arms. The ligand binds each anion with a 1:1 binding mode in water, exhibiting strong selectivity for sulfate; which is further supported by ESI-MS and DFT calculations.
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