ArticleAngewandte Chemie (International ed. in English)2017
Palladium-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
21 citing papers in PubMed.
- Efficient Preparation of Homogenous Antibody Conjugates via Glycosite-Specific Transglycosylation Enabled by Readily Available Glycosyl Donors.Angewandte Chemie (International ed. in English) · 2026Article
- Dissecting Tin-Based Activation and Anomerization Pathways in Carbohydrate Chemistry.ACS omega · 2026Article
- Catalytic Strategies for Stereoselective Carbohydrate Synthesis: Emerging Concepts for Accessing Challenging Glycosides.Angewandte Chemie (International ed. in English) · 2025Review
- Article
- Synthesis of 2-Deoxyglycosides with Exclusive β-Configuration Using 2-SAc Glycosyl Bromide Donors.Molecules (Basel, Switzerland) · 2025Article
- Harnessing Multistep Chalcogen Bonding Activation in the α-Stereoselective Synthesis of Iminoglycosides.Journal of the American Chemical Society · 2024Article
- Characterization and Fate of a Septanosyl Ferrier Cation in the Gas and Solution Phases.The Journal of organic chemistry · 2023Article
- Development of α-Selective Glycosylation with l-Oleandral and Its Application to the Total Synthesis of Oleandrin.Organic letters · 2023Article
- Stereoselective Synthesis of 2-Deoxythiosugars from Glycals.Molecules (Basel, Switzerland) · 2022Article
- P(v) intermediate-mediated E1cB elimination for the synthesis of glycals.Chemical science · 2022Article
- Recent Advances in Stereoselective ChemicalFrontiers in molecular biosciences · 2022Review
- Convergent Palladium-Catalyzed Stereospecific Arginine Glycosylation Using Glycals.Organic letters · 2021Article
- Palladium(II)-assisted activation of thioglycosides.Organic & biomolecular chemistry · 2021Article
- Iridium-promoted deoxyglycoside synthesis: stereoselectivity and mechanistic insight.Chemical science · 2020Article
- Modular continuous flow synthesis of orthogonally protected 6-deoxy glucose glycals.Organic & biomolecular chemistry · 2020Article
- Improved Synthesis of Sulfur-Containing Glycosides by Suppressing Thioacetyl Migration.Frontiers in chemistry · 2020Article
- Substrate-Controlled Direct α-Stereoselective Synthesis of Deoxyglycosides from Glycals Using B(CThe Journal of organic chemistry · 2019Article
- Methods for 2-Deoxyglycoside Synthesis.Chemical reviews · 2018Review
- Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals.Journal of the American Chemical Society · 2017Article
- Palladium-Catalyzed α-Stereoselective O-Glycosylation of O(3)-Acylated Glycals.Organic letters · 2017Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Palladium(II) in combination with a monodentate phosphine ligand enables the unprecedented direct and α-stereoselective catalytic synthesis of deoxyglycosides from glycals. Initial mechanistic studies suggest that in the presence of N-phenyl-2-(di-tert-butylphosphino)pyrrole as the ligand, the reaction proceeds via an alkoxy palladium intermediate that increases the proton acidity and oxygen nucleophilicity of the alcohol. The method is demonstrated with a wide range of glycal donors and acceptors, including substrates bearing alkene functionalities.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.