ArticleAngewandte Chemie (International ed. in English)2017
Controlled Covalent Functionalization of Thermally Reduced Graphene Oxide To Generate Defined Bifunctional 2D Nanomaterials.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Correlative Chemical Imaging to Reveal the Nature of Different Commercial Graphene Materials.Small methods · 2026Article
- Two-Dimensional Polycyclodextrins for Strong Multivalent Host-Guest Interactions at Biointerfaces.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- The Role and Future of Functional Graphenic Materials in Biomedical and Human Health Applications.Biomacromolecules · 2025Review
- Thermoresponsive and antibacterial two-dimensional polyglycerol-Journal of nanostructure in chemistry · 2022Article
- Heavy-Atom Quantum Tunnelling in Spin Crossovers of Nitrenes.Angewandte Chemie (International ed. in English) · 2022Article
- Modification of carbon-based nanomaterials by polyglycerol: recent advances and applications.RSC advances · 2021Review
- Review
- Graphene-Assisted Synthesis of 2D Polyglycerols as Innovative Platforms for Multivalent Virus Interactions.Advanced functional materials · 2021Article
- Chiral Graphene Hybrid Materials: Structures, Properties, and Chiral Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2021Review
- Graphene Sheets with Defined Dual Functionalities for the Strong SARS-CoV-2 Interactions.Small (Weinheim an der Bergstrasse, Germany) · 2021Article
- Functionalized Graphene Platforms for Anticancer Drug Delivery.International journal of nanomedicine · 2021Review
- Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization.Nature chemistry · 2018Article
- Controlled Covalent Functionalization of Thermally Reduced Graphene Oxide To Generate Defined Bifunctional 2D Nanomaterials.Angewandte Chemie (International ed. in English) · 2017Article
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Authors and funding
10 authors.
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Abstract
A controlled, reproducible, gram-scale method is reported for the covalent functionalization of graphene sheets by a one-pot nitrene [2+1] cycloaddition reaction under mild conditions. The reaction between commercially available 2,4,6-trichloro-1,3,5-triazine and sodium azide with thermally reduced graphene oxide (TRGO) results in defined dichlorotriazine-functionalized sheets. The different reactivities of the chlorine substituents on the functionalized graphene allow stepwise post-modification by manipulating the temperature. This new method provides unique access to defined bifunctional 2D nanomaterials, as exemplified by chiral surfaces and multifunctional hybrid architectures.
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