ArticleOrganic letters2017
Organocatalyzed, Photoredox Heteroarylation of 2-Trifluoroboratochromanones via C-H Functionalization.
Article in Organic letters, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- A unified strategy for α-alkoxyalkyl radical generationOrganic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Parallel Minisci Reaction ofACS organic & inorganic Au · 2024Article
- The Impact of Boron Hybridisation on Photocatalytic Processes.Angewandte Chemie (International ed. in English) · 2022Review
- Recent developments in photoredox-catalyzed remoteBeilstein journal of organic chemistry · 2020Review
- Glycosyl Cross-Coupling of Anomeric Nucleophiles: Scope, Mechanism, and Applications in the Synthesis of Aryl C-Glycosides.Journal of the American Chemical Society · 2017Article
- Late-Stage C-H Alkylation of Heterocycles and 1,4-Quinones via Oxidative Homolysis of 1,4-Dihydropyridines.Journal of the American Chemical Society · 2017Article
- Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals.Chemistry (Weinheim an der Bergstrasse, Germany) · 2017Article
- Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer.Journal of the American Chemical Society · 2017Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Heteroarylation via C-H functionalization has been synthetically challenging, but such transformations represent an atom-economical and highly convergent route toward complex molecules. Reported herein is a photoredox-catalyzed coupling between 2-trifluoroborato-4-chromanones and various heteroarenes through a Minisci pathway. Mesitylacridinium perchlorate, an organic photocatalyst, proved to be a better photocatalyst than transition-metal counterparts for such transformations. To highlight the utility of this approach, a library of unprecedented heteroaryl-substituted chromanones was generated that was composed of numerous, specifically substituted molecules containing a broad range of functional groups.
Identifiers
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Registered trials
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