Evidence map›Paper›PMID 28150499›Full record

ArticleThe Journal of organic chemistry2017

Synthesis and Spectroscopic Investigation of a Series of Push-Pull Boron Dipyrromethenes (BODIPYs).

Sunting Xuan, Ning Zhao, Xiangyi Ke, Zehua Zhou, Frank R Fronczek, Karl M Kadish, Kevin M Smith, M Graça H Vicente

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Sunting XuanDepartment of Chemistry, Louisiana State University , Baton Rouge, Louisiana 70803, United States.
Ning ZhaoDepartment of Chemistry, Louisiana State University , Baton Rouge, Louisiana 70803, United States.
Xiangyi KeDepartment of Chemistry, University of Houston , Houston, Texas 77204, United States.
Zehua ZhouDepartment of Chemistry, Louisiana State University , Baton Rouge, Louisiana 70803, United States.
Frank R FronczekDepartment of Chemistry, Louisiana State University , Baton Rouge, Louisiana 70803, United States.
Karl M KadishDepartment of Chemistry, University of Houston , Houston, Texas 77204, United States.
Kevin M SmithDepartment of Chemistry, Louisiana State University , Baton Rouge, Louisiana 70803, United States.
M Graça H VicenteDepartment of Chemistry, Louisiana State University , Baton Rouge, Louisiana 70803, United States.ORCID 0000-0002-4429-7868

Funding

CRC-specific near-IR agents for tumor imagingR01CA179902 · NCI · LOUISIANA STATE UNIV A&M COL BATON ROUGE · PI VICENTE, MARIA DA GRACA HENRIQUES · 2014 to 2017
$1.2M
NCI NIH HHS R01 CA179902
6 · The paper itself

Abstract

A series of push-pull BODIPYs bearing multiple electron-donating and electron-acceptor groups were synthesized regioselectively from 2,3,5,6,8-pentachloro-BODIPY, and characterized by NMR spectroscopy, HRMS, and X-ray crystallography. The influence of the push-pull substituents on the spectroscopic and electrochemical properties of BODIPYs was investigated. Bathochromic shifts were observed for both absorbance (up to 37 nm) and emission (up to 60 nm) in different solvents upon introduction of the push-pull moieties. DFT calculations, consistent with the spectroscopic and cyclic voltammetry studies, show decreased HOMO-LUMO energy gaps upon the installation of the push-pull moieties. BODIPY 7 bearing thienyl groups on the 2 and 6 positions showed the largest λ

Indexed as

BoronCrystallography, X-RayFluorescenceMolecular StructurePorphobilinogenQuantum TheorySpectrum AnalysisBorondipyrromethenePorphobilinogen

Identifiers

PMID28150499
PMCPMC5510570

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.