ArticleProceedings of the National Academy of Sciences of the United States of America2017
Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Comparative study on the role of extracts of male and female of jojoba's leaves in the green synthesis of α-MnOScientific reports · 2026Article
- Predicting rates of manganese oxide reduction from thermodynamic driving forces and structural properties.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Manganese (Hydr)oxides record the dynamic evolution of a million-year Hesperian Ocean in Utopia Planitia, Mars.Nature communications · 2026Article
- Understanding the role of manganese oxides in retaining harmful metals: Insights into oxidation and adsorption mechanisms at microstructure level.Eco-Environment & Health · 2024Review
- Vanadate Retention by Iron and Manganese Oxides.ACS earth & space chemistry · 2022Article
- Nanoscale Hydration in Layered Manganese Oxides.Langmuir : the ACS journal of surfaces and colloids · 2021Article
- Diversity in the Family of Manganese Oxides at the Nanoscale: From Fundamentals to Applications.ACS omega · 2020Review
- Synthesis, Characterization, and Optimization of Magnetoelectric BaTiONanomaterials (Basel, Switzerland) · 2020Article
- A Hollow-Structured Manganese Oxide Cathode for Stable Zn-MnO₂ Batteries.Nanomaterials (Basel, Switzerland) · 2018Article
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Authors and funding
2 authors.
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Abstract
Manganese oxides with layer and tunnel structures occur widely in nature and inspire technological applications. Having variable compositions, these structures often are found as small particles (nanophases). This study explores, using experimental thermochemistry, the role of composition, oxidation state, structure, and surface energy in the their thermodynamic stability. The measured surface energies of cryptomelane, sodium birnessite, potassium birnessite and calcium birnessite are all significantly lower than those of binary manganese oxides (Mn
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