Evidence map›Paper›PMID 28103018›Full record

ReviewChemical reviews2017

Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Courtney E Elwell, Nicole L Gagnon, Benjamin D Neisen, Debanjan Dhar, Andrew D Spaeth, Gereon M Yee, William B Tolman

Abstract readReview
In one paragraph

Review in Chemical reviews, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 165 papers.

0numbers the graph read from it
0cells of the map it votes in
165citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

165 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Review
  8. Review
  9. PotassiumInorganic chemistry · 2026
    Article
  10. Article
  11. Article
  12. Article
  13. Unprecedented Formation of a Formally Cu(III) Trifluoromethyl Hydroxide Tetramer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  14. Review
  15. Review
  16. Article
  17. Article
  18. HACS electrochemistry · 2025
    Article
  19. CO Oxidation Catalyzed by Single-Atom Rh@MOF-808 via a Peroxo-Mediated Eley-Rideal Mechanism.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025
    Article
  20. Article

105 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Courtney E ElwellDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
Nicole L GagnonDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
Benjamin D NeisenDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
Debanjan DharDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.ORCID 0000-0002-3027-0226
Andrew D SpaethDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.ORCID 0000-0002-4265-6150
Gereon M YeeDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
William B TolmanDepartment of Chemistry, Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.ORCID 0000-0002-2243-6409

Funding

Synthetic Modeling of Copper Protein Active SitesR37GM047365 · NIGMS · UNIVERSITY OF MINNESOTA · PI TOLMAN, WILLIAM B · 2008 to 2017
$3.3M
NIGMS NIH HHS R37 GM047365
6 · The paper itself

Abstract

A longstanding research goal has been to understand the nature and role of copper-oxygen intermediates within copper-containing enzymes and abiological catalysts. Synthetic chemistry has played a pivotal role in highlighting the viability of proposed intermediates and expanding the library of known copper-oxygen cores. In addition to the number of new complexes that have been synthesized since the previous reviews on this topic in this journal (Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P. Chem. Rev. 2004, 104, 1013-1046 and Lewis, E. A.; Tolman, W. B. Chem. Rev. 2004, 104, 1047-1076), the field has seen significant expansion in the (1) range of cores synthesized and characterized, (2) amount of mechanistic work performed, particularly in the area of organic substrate oxidation, and (3) use of computational methods for both the corroboration and prediction of proposed intermediates. The scope of this review has been limited to well-characterized examples of copper-oxygen species but seeks to provide a thorough picture of the spectroscopic characteristics and reactivity trends of the copper-oxygen cores discussed.

Indexed as

CopperMolecular StructureOxygenSpectrum AnalysisCopperOxygen

Identifiers

PMID28103018
PMCPMC5963733

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.