ArticleInorganic chemistry2017
Modulating the Primary and Secondary Coordination Spheres within a Series of Co
Article in Inorganic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Bimetallic Chemistry by Design: Approaches to the Development of Multifunctional Ligands.Coordination chemistry reviews · 2026Article
- Harnessing Benzoyl-Urea Secondary-Sphere Hydrogen-Bonding to Enhance Oxygen Evolution Catalysis by Cobalt Corroles.Small science · 2026Article
- A CoInorganic chemistry · 2024Article
- Modulation of the Bonding between Copper and a Redox-Active Ligand by Hydrogen Bonds and Its Effect on Electronic Coupling and Spin States.Journal of the American Chemical Society · 2024Article
- Investigation of iron-ammine and amido complexes within a CDalton transactions (Cambridge, England : 2003) · 2021Article
- Regulating the Basicity of Metal-Oxido Complexes with a Single Hydrogen Bond and Its Effect on C-H Bond Cleavage.Journal of the American Chemical Society · 2019Article
- Manganese-Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand.Inorganic chemistry · 2018Article
- Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity.Chemical science · 2018Article
- Hydrogen Bonds Dictate OJournal of the American Chemical Society · 2018Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
The interplay between the primary and secondary coordination spheres is crucial to determining the properties of transition metal complexes. To examine these effects, a series of trigonal bipyramidal Co-OH complexes have been prepared with tripodal ligands that control both coordination spheres. The ligands contain a combination of either urea or sulfonamide groups that control the primary coordination sphere through anionic donors in the trigonal plane and the secondary coordination sphere through intramolecular hydrogen bonds. Variations in the anion donor strengths were evaluated using electronic absorbance spectroscopy and a qualitative ligand field analysis to find that deprotonated urea donors are stronger field ligands than deprotonated sulfonamides. Structural variations were found in the Co
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Registered trials
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