ArticleInorganic chemistry2017
Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II).
Article in Inorganic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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Who cites it
11 citing papers in PubMed.
- Trimethylsilyldiazomethane Disassembly at a Three-Fold Symmetric Iron Site.Inorganic chemistry · 2024Article
- Valence Delocalization and Metal-Metal Bonding in Carbon-Bridged Mixed-Valence Iron Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Sulfur-Ligated [2Fe-2C] Clusters as Synthetic Model Systems for Nitrogenase.Inorganic chemistry · 2023Article
- Synthesis of a FeJournal of the American Chemical Society · 2023Article
- High Magnetic Anisotropy of a Square-Planar Iron-Carbene Complex.Inorganic chemistry · 2021Article
- Cobalt Diazo-Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate.Angewandte Chemie (International ed. in English) · 2021Article
- The influences of carbon donor ligands on biomimetic multi-iron complexes for NChemical science · 2020Article
- A Chiral Macrocyclic Tetra-N-Heterocyclic Carbene Yields an "All Carbene" Iron Alkylidene Complex.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N-N Bond Cleavage.Angewandte Chemie (International ed. in English) · 2019Article
- From Ylides to Doubly Yldiide-Bridged Iron(II) High Spin Dimers via Self-Protolysis.Inorganic chemistry · 2019Article
- Incorporating light atoms into synthetic analogues of FeMoco.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
The addition of (trimethylsilyl)diazomethane and its conjugate base to iron β-diketiminate precursors gives novel dinuclear complexes in which the bridges are either diazomethane derivatives or an alkylidene. One product is an unusual bridging alkylidene complex containing two three-coordinate iron(II) centers. On the other hand, syntheses using the deprotonated diazomethane give two bridging diazomethyl species with binding modes that have not been observed in iron complexes previously. In the presence of a coordinating tetrahydrofuran solvent, a diiron(II) compound with μ-N bridges rearranges to a more stable isomer with μ-N,C bridges, a process that is accompanied by a 1,3-shift of a silyl group.
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Registered trials
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