ArticleACS macro letters2016
Visible-Light-Initiated Thiol-Michael Addition Polymerizations with Coumarin-Based Photobase Generators: Another Photoclick Reaction Strategy.
Article in ACS macro letters, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Photoinduced Ring-Opening Polymerization of N-Carboxyanhydrides for the Preparation of Cross-Linked Polypeptide Gels.Angewandte Chemie (International ed. in English) · 2026Article
- Mechanobiological Dynamics-Inspired Mechanomodulatory Biomaterials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Polymers and light: a love-hate relationship.Chemical science · 2025Review
- Visible and near-infrared light-induced photoclick reactions.Nature reviews. Chemistry · 2024Review
- Record release of tetramethylguanidine using a green light activated photocage for rapid synthesis of soft materials.Chemical science · 2023Article
- Rapid hydrogel formation via tandem visible light photouncaging and bioorthogonal ligation.Cell reports. Physical science · 2022Article
- Photoclick Chemistry: A Bright Idea.Chemical reviews · 2021Review
- Visible-to-NIR-Light Activated Release: From Small Molecules to Nanomaterials.Chemical reviews · 2020Article
- Thiol-Ene Photopolymerization: Scaling Law and Analytical Formulas for Conversion Based on Kinetic Rate and Thiol-Ene Molar Ratio.Polymers · 2019Article
- Modeling the Optimal Conditions for Improved Efficacy and Crosslink Depth of Photo-Initiated Polymerization.Polymers · 2019Article
- Assessment of TEMPO as a Thermally Activatable Base Generator and Its Use in Initiation of Thermally-Triggered Thiol-Michael Addition Polymerizations.Polymer chemistry · 2018Article
- Dental Restorative Materials Based on Thiol-Michael Photopolymerization.Journal of dental research · 2018Article
- Article
- Wavelength-Selective Sequential Polymer Network Formation Controlled with a Two-Color Responsive Initiation System.Macromolecules · 2017Article
- Polymeric Biomaterials: Diverse Functions Enabled by Advances in Macromolecular Chemistry.Macromolecules · 2017Article
- Mechanistic Kinetic Modeling of Thiol-Michael Addition Photopolymerizations via Photocaged "Superbase" Generators: An Analytical Approach.Macromolecules · 2016Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
An efficient visible-light-sensitive photobase generator for thiol-Michael addition reactions was synthesized and evaluated. This highly reactive catalyst was designed by protecting a strong base (tetramethyl guanidine, TMG) with a visible-light-responsive group which was a coumarin derivative. The coumarin-coupled TMG was shown to exhibit extraordinary catalytic activity toward initiation of the thiol-Michael reaction, including thiol-Michael addition-based polymerization, upon visible-light irradiation, leading to a stoichiometric reaction of both thiol and vinyl functional groups. Owing to its features, this visible-light photobase generator enables homogeneous network formation in thiol-Michael polymerizations and also has the potential to be exploited in other visible-light-induced, base-catalyzed thiol-click processes such as thiol-isocynate and thiol-epoxy network-forming reactions.
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Registered trials
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