ArticleScientific reports2016
New Formyl Phloroglucinol Meroterpenoids from the Leaves of Eucalyptus robusta.
Article in Scientific reports, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Prodigious biodegradation of polycyclic aromatic fluorene with manganese oxide nanoparticles from Stenotrophomonas sp.Biodegradation · 2025Article
- New Meroterpenoid Derivatives from the Pomegranate-Derived Endophytic FungusMolecules (Basel, Switzerland) · 2023Article
- Biological activities of meroterpenoids isolated from different sources.Frontiers in pharmacology · 2022Review
- Meroterpenoids: A Comprehensive Update Insight on Structural Diversity and Biology.Biomolecules · 2021Review
- UPLC-PDA-Q Exactive Orbitrap-MS profiling of the lipophilic compounds product isolated fromHeliyon · 2020Article
- Phloroglucinol Mediated Plant Regeneration ofPlants (Basel, Switzerland) · 2020Article
- Quantification and Localization of Formylated Phloroglucinol Compounds (FPCs) inFrontiers in plant science · 2019Article
- Eucalyptusdimers A-C, Dimeric Phloroglucinol-Phellandrene Meroterpenoids from Eucalyptus robusta.Organic letters · 2018Article
- Evolution of a Strategy for the Enantioselective Total Synthesis of (+)-Psiguadial B.The Journal of organic chemistry · 2018Article
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Seven new formyl phloroglucinol meroterpenoids (FPMs), namely eucalrobusones J-P (1-7), as well as three known ones (8-10) were isolated from the leaves of Eucalyptus robusta. Their structures were elucidated by spectroscopic data analysis, and their absolute configurations were determined by applications of the Snatzke's helicity rule and the electron circular dichroism (ECD) calculation. These FPMs are diverse in coupling patterns between phloroglucinol and sesquiterpenoid units, forming novel polycyclic ring systems. Compound 1 possesses a new carbon skeleton that a 1-oxaspiro[5.6]dodecane core is formed through C-14 rather than C-4 of the aromadendrane moiety. Compound 2 features a novel 6/7/5 ring-fused 6-oxabicyclo[3.2.2]nonane skeleton. Compounds 3-5 are rare aristolane-based FPMs. By forming different oxo bridges, compound 3 is the first sample of FPM with benzo-dihydrofuran structure, and compound 4 possesses a novel 6/6/6/6/3-fused pentacyclic skeleton. Compounds 1, 6, and 8 exhibited significant antifungal activities against Candida glabrata with MIC
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