ArticleAngewandte Chemie (International ed. in English)2017
Versatile Homoallylic Boronates by Chemo-, S
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- Enantioselective Syntheses of Secondary Alkylboronates via Asymmetric Regioselective Reduction of 1,3-Dienylboronates.Angewandte Chemie (International ed. in English) · 2026Article
- Chiral Copper Catalysis in Enantioselective Domino Reactions.Molecules (Basel, Switzerland) · 2025Review
- Design Approaches That Utilize Ionic Interactions to Control Selectivity in Transition Metal Catalysis.Chemical reviews · 2025Review
- Anti-Markovnikov hydroallylation reaction of alkenes via scandium-catalyzed allylic C‒H activation.Nature communications · 2025Article
- Recent advances in allylation of chiral secondary alkylcopper species.Beilstein journal of organic chemistry · 2025Review
- The current utility and future potential of multiborylated alkanes.Nature reviews. Chemistry · 2024Review
- Organophosphates as Versatile Substrates in Organic Synthesis.Molecules (Basel, Switzerland) · 2024Review
- Asymmetric synthesis of chiral (thio)chromanes and exploration on their structure-activity relationship in macrophages.RSC advances · 2023Article
- Ligand Control in Co-Catalyzed Regio- and Enantioselective Hydroboration: Homoallyl Secondary Boronates via Uncommon 4,3-Hydroboration of 1,3-Dienes.Journal of the American Chemical Society · 2023Article
- Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands.Molecules (Basel, Switzerland) · 2021Review
- Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C-C, C-B, C-H, and C-Si Bonds.Angewandte Chemie (International ed. in English) · 2020Review
- Synthesis of Pyrroles through the CuH-Catalyzed Coupling of Enynes and Nitriles.Journal of the American Chemical Society · 2020Article
- Cascade CuH-Catalysed Conversion of Alkynes to Enantioenriched 1,1-Disubstituted Products.Nature catalysis · 2020Article
- Copper-Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis.Journal of the American Chemical Society · 2019Article
- 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2019Article
- CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence.Journal of the American Chemical Society · 2019Article
- Racemic Vinylallenes in Catalytic Enantioselective Multicomponent Processes: Rapid Generation of Complexity through 1,6-Conjugate Additions.Angewandte Chemie (International ed. in English) · 2019Article
- Enantioselective and site-specific copper-catalyzed reductive allyl-allyl cross-coupling of allenes.Chemical science · 2019Article
- Diastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenes.Chemical science · 2018Article
- Cu-catalyzed enantioselective synthesis of tertiary benzylic copper complexes and theirChemical science · 2018Article
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Authors and funding
3 authors.
Funding
Abstract
A highly chemo-, diastereo- and enantioselective catalytic method that efficiently combines a silyl hydride, vinyl-B(pin) (pin=pinacolato) and (E)-1,2-disubstituted allylic phosphates is introduced. Reactions, best promoted by a Cu-based complex with a chiral sulfonate-containing N-heterocyclic carbene, are broadly applicable. Aryl-, heteroaryl-, alkenyl-, alkynyl- and alkyl-substituted allylic phosphates may thus be converted to the corresponding homoallylic boronates and then alcohols (after C-B bond oxidation) in 46-91 % yield and in up to >98 % S
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