ArticleJournal of the American Chemical Society2016
Synchronized Offset Stacking: A Concept for Growing Large-Domain and Highly Crystalline 2D Covalent Organic Frameworks.
Article in Journal of the American Chemical Society, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 51 papers.
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Who cites it
51 citing papers in PubMed.
- Precise molecular sieving in polycrystalline covalent organic framework membranes.Science advances · 2026Article
- Humidity-Guided In Situ Polymerization for Controlled Formation of Smooth, Oriented Covalent Organic Framework Films.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Luminescent Covalent-Organic Frameworks: Design Strategies, Photophysical Mechanisms, and Applications.Small methods · 2026Review
- Spatially Separated Redox Centers in One-Dimensional SpAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Coordination-Induced Dispersion of Covalent Organic Frameworks for Organic Solar Cells With 21.03% Efficiency.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Single Crystals of Perylene Diimide-Based Two-Dimensional Covalent Organic Frameworks.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Dynamic covalent organic frameworks.Chemical science · 2026Review
- Constructing out-of-plane oriented two-dimensional covalent organic framework films for stretchable electronics.Nature communications · 2025Article
- Catalyst-Driven Improvements in Conventional Methods for Imine-Linked Covalent Organic Frameworks.Molecules (Basel, Switzerland) · 2025Review
- Rolling two-dimensional covalent organic framework (COF) sheets into one-dimensional electronic and proton-conductive nanotubes.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Interlocked 2D Covalent Organic Frameworks from Overcrowded Nodes.Journal of the American Chemical Society · 2025Article
- Solvent-responsive covalent organic framework membranes for precise and tunable molecular sieving.Science advances · 2024Article
- Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024Review
- Dimensionality and Molecular Packing Control of Covalent Organic Frameworks through Pendant Group Design.Journal of the American Chemical Society · 2024Article
- Structural Reassignment of Covalent Organic Framework-Supported Palladium Species: Heterogenized Palladacycles as Efficient Catalysts for Sustainable C-H Activation.ACS central science · 2024Article
- Probing Defects in Covalent Organic Frameworks.ACS applied materials & interfaces · 2024Review
- Dynamic two-dimensional covalent organic frameworks.Nature chemistry · 2024Article
- Design and synthesis of broadband absorption covalent organic framework for efficient artificial photocatalytic amine coupling.Nature communications · 2024Article
- Development of surface-enhanced Raman scattering-sensing Method by combining novel Ag@Au core/shell nanoparticle-based SERS probe with hybridization chain reaction for high-sensitive detection of hepatitis C virus nucleic acid.Analytical and bioanalytical chemistry · 2024Article
- Encoding ordered structural complexity to covalent organic frameworks.Nature communications · 2024Article
Corrections and comments
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Authors and funding
14 authors.
Funding
Abstract
Covalent organic frameworks (COFs), formed by reversible condensation of rigid organic building blocks, are crystalline and porous materials of great potential for catalysis and organic electronics. Particularly with a view of organic electronics, achieving a maximum degree of crystallinity and large domain sizes while allowing for a tightly π-stacked topology would be highly desirable. We present a design concept that uses the 3D geometry of the building blocks to generate a lattice of uniquely defined docking sites for the attachment of consecutive layers, thus allowing us to achieve a greatly improved degree of order within a given average number of attachment and detachment cycles during COF growth. Synchronization of the molecular geometry across several hundred nanometers promotes the growth of highly crystalline frameworks with unprecedented domain sizes. Spectroscopic data indicate considerable delocalization of excitations along the π-stacked columns and the feasibility of donor-acceptor excitations across the imine bonds. The frameworks developed in this study can serve as a blueprint for the design of a broad range of tailor-made 2D COFs with extended π-conjugated building blocks for applications in photocatalysis and optoelectronics.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.