ArticleChemical reviews2017
Transition-Metal-Catalyzed C-H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds.
Article in Chemical reviews, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 61 papers.
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Who cites it
61 citing papers in PubMed.
- Enantioselective Iridium-Catalyzed Intramolecular Hydroarylation of (Hetero)Arene-Tethered Prochiral Diketones.Journal of the American Chemical Society · 2026Article
- Selective Functionalization of 1-substituted-3-arylquinoxalin-2(1RSC advances · 2026Review
- Heterogeneous photocatalytic aldehyde alkylative amination for multicomponent synthesis of α-branched amines.National science review · 2026Article
- Electron donor-acceptor complex offers a diverse approach for carbonyl alkylative amination.Chemical science · 2025Article
- Regioselective Ru(ii)-catalyzed C-H alkenylation and annulation of indoles: a direct approach to fused lactone scaffolds.RSC advances · 2025Article
- Ni/NHC-catalyzed C5-H alkylation and alkenylation of challenging furan(thiophene)-2-carboxaldehydes enabled by recyclable imine protecting group.Communications chemistry · 2025Article
- Molecular Dynamics of the Davies Ambimodal C-H Functionalization/Cope Rearrangement Reaction.The Journal of organic chemistry · 2024Article
- Organocatalytic aromatization-promoted umpolung reaction of imines.Nature chemistry · 2024Article
- Rhodium-catalyzed annulation of hydrazines with vinylene carbonate to synthesize unsubstituted 1-aminoindole derivatives.RSC advances · 2024Article
- The crucial role of silver(I)-salts as additives in C-H activation reactions: overall analysis of their versatility and applicability.Chemical Society reviews · 2023Review
- Intermolecular Metal-Catalyzed C‒C Coupling of Unactivated Alcohols or Aldehydes for Convergent Ketone Construction beyond Premetalated Reagents.ACS catalysis · 2023Article
- Sulfoximine Assisted C-H Activation and Annulation via Vinylene Transfer: Access to Unsubstituted Benzothiazines.Molecules (Basel, Switzerland) · 2023Article
- Rh-Catalyzed [3+2] Annulation of Cyclic Ketimines and Alkynyl Chloride: A Strategy for Accessing Unsymmetrically Substituted and Highly Functionalizable Indenes.Organic letters · 2022Article
- C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles.Journal of the American Chemical Society · 2022Article
- C-H bond activation and sequential addition to two different coupling partners: a versatile approach to molecular complexity.Chemical Society reviews · 2022Review
- Mapping Catalyst-Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Insights into the Activation Mode of α-Carbonyl Sulfoxonium Ylides in Rhodium-Catalyzed C-H Activation: A Theoretical Study.ChemistryOpen · 2022Article
- RhodiumChemical science · 2022Article
- Stereoselective Synthesis of Allenyl Alcohols by Cobalt(III)-Catalyzed Sequential C-H Bond Addition to 1,3-Enynes and Aldehydes.Angewandte Chemie (International ed. in English) · 2022Article
- Directing group assisted rhodium catalyzedChemical science · 2022Article
1 more citing papers are in PubMed but not listed here.
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Authors and funding
3 authors.
Funding
Abstract
The transition-metal-catalyzed addition of C-H bonds to carbonyls, imines, and related polarized π bonds has emerged as a particularly efficient and powerful approach for the construction of an incredibly diverse array of heteroatom-substituted products. Readily available and stable inputs are typically employed, and reactions often proceed with very high functional group compatibility and without the production of waste byproducts. Additionally, many transition-metal-catalyzed C-H bond additions to polarized π bonds occur within cascade reaction sequences to provide rapid access to a diverse array of different heterocyclic as well as carbocyclic products. This review highlights the diversity of transformations that have been achieved, catalysts that have been used, and types of products that have been prepared through the transition-metal-catalyzed addition of C-H bonds to carbonyls, imines, and related polarized π bonds.
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Registered trials
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