ArticleChemistry (Weinheim an der Bergstrasse, Germany)2017
Intermolecular Aryl C-H Amination through Sequential Iron and Copper Catalysis.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed, 38 citations in OpenAlex.
- Unprecedented Copper/Iron-Cocatalyzed Homocoupling of Propargyl Ethers to Conjugated Benzofurans.JACS Au · 2025Article
- Synthesis of β-Pyridyl α-Amino Acids: Conformationally Sensitive Charge Transfer-Based Fluorophores.Organic letters · 2024Article
- Trifluoromethylthiolation of Arenes Using Lewis Acid and Lewis Base Dual Catalysis.The Journal of organic chemistry · 2024Article
- Regioselective C-H Thiocyanation of Arenes by Iron(III) Chloride Catalysis.The Journal of organic chemistry · 2023Article
- Triflamides and Triflimides: Synthesis and Applications.Molecules (Basel, Switzerland) · 2022Review
- Recent Progress Concerning theMolecules (Basel, Switzerland) · 2021Review
- Synthesis of Benzo[Organic letters · 2020Article
- Intermolecular Aryl C-H Amination through Sequential Iron and Copper Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2017Article
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Authors and funding
4 authors at 1 institution in 1 country.
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Abstract
A mild, efficient and regioselective method for para-amination of activated arenes has been developed through a combination of iron and copper catalysis. A diverse range of products were obtained from an operationally simple one-pot, two-step procedure involving bromination of the aryl substrate with the powerful Lewis acid iron(III) triflimide, followed by a copper(I)-catalysed N-arylation reaction. This two-step dehydrogenative process for the regioselective coupling of aromatic C-H bonds with non-activated amines was applicable to anisole-, phenol-, aniline- and acetanilide-type aryl compounds. Importantly, the arene substrates were used as the limiting reagent and required no protecting-group manipulations during the transformation.
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