ArticleChemistry (Weinheim an der Bergstrasse, Germany)2017
Ruthenium-Catalyzed C-H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- The Mechanism of Ruthenium-Catalyzed Directed C─H Arylation of Arenes: The Key Role of Bis-Cyclometalated Intermediates.Angewandte Chemie (International ed. in English) · 2025Article
- Ruthenium Catalyzed Ortho-Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts.Angewandte Chemie (International ed. in English) · 2025Article
- An air- and moisture-stable ruthenium precatalyst for diverse reactivity.Nature chemistry · 2024Article
- The crucial role of silver(I)-salts as additives in C-H activation reactions: overall analysis of their versatility and applicability.Chemical Society reviews · 2023Review
- Brønsted acid catalyzed remote C6 functionalization of 2,3-disubstituted indoles with β,γ-unsaturated α-ketoester.Frontiers in chemistry · 2022Article
- Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Regioselective C-H Functionalization of the Six-Membered Ring of the 6,5-Fused Heterocyclic Systems: An Overview.Molecules (Basel, Switzerland) · 2021Review
- Tailored quinones support high-turnover Pd catalysts for oxidative C-H arylation with OScience (New York, N.Y.) · 2020Article
- Insights into Ruthenium(II/IV)-Catalyzed Distal C-H Oxygenation by Weak Coordination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Regiodivergent C-H and Decarboxylative C-C Alkylation by Ruthenium Catalysis: ortho versus meta Position-Selectivity.Angewandte Chemie (International ed. in English) · 2020Article
- Photo-Induced Ruthenium-Catalyzed C-H Arylations at Ambient Temperature.Angewandte Chemie (International ed. in English) · 2020Article
- Ruthenium-Catalyzed C-H Arylation of 1-Naphthol with Aryl and Heteroaryl Halides.The Journal of organic chemistry · 2019Article
- Article
- Benzoate Cyclometalation Enables Oxidative Addition of Haloarenes at a Ru(II) Center.Journal of the American Chemical Society · 2018Article
- A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.Chemical Society reviews · 2018Review
- C4-H indole functionalisation: precedent and prospects.Chemical science · 2018Review
- The Strong β-CFChemCatChem · 2018Article
- Cobalt-Catalyzed Coupling of Benzoic Acid C-H Bonds with Alkynes, Styrenes, and 1,3-Dienes.Angewandte Chemie (International ed. in English) · 2018Article
- Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination.Organic letters · 2017Article
- Highly chemoselective ruthenium(ii)-catalyzed direct arylation of cyclic andChemical science · 2017Article
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Authors and funding
7 authors.
Funding
Abstract
Herein we report the first Ru-catalyzed C-H arylation of benzoic acids with readily available aryl (pseudo)halides. The reaction, which does not require the use of silver salt additives, allows the arylation of previously challenging hindered benzoic acids and the use of generally unreactive ortho-substituted halorarenes. Furthermore, our new protocol can efficiently be applied to indole carboxylic acids, thus allowing access to C7-, C6-, C5- and C4-arylated indole compounds, a departure from the classical enhanced reactivity of the C2 and C3 positions of indole.
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