ArticleNature chemistry2016
Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.
Article in Nature chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 44 papers.
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Who cites it
44 citing papers in PubMed, 240 citations in OpenAlex.
- Bioinspired Copper(II) Complexes With N,S-Donor Ligands: Structure-Activity Relationships and Mechanistic Insights for Aqueous Hydrogen Evolution Reaction.ChemSusChem · 2026Article
- Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen.Journal of the American Chemical Society · 2026Article
- Synthesis, Properties, and Electrochemical Proton Reduction of a Homoleptic Tetrathiolato Ni-Site Model of [NiFe]-Hydrogenase.Inorganic chemistry · 2025Article
- NRVS Spectroscopy Resolves Distinct Bridging Hydride Intermediates in [NiFe]-Hydrogenase.Journal of the American Chemical Society · 2025Article
- Bimetallic [Co/K] hydrogen evolution catalyst for electrochemical terminal C-H functionalization.Nature communications · 2025Article
- Tuning the Electronic and Molecular Structures of Bioinspired Heterodinuclear NiFe Catalyst for Enhanced Catalytic HACS organic & inorganic Au · 2025Article
- Harnessing conductive materials to reshape sewer microbiomes and mitigate corrosion from sulfide and hydrogen sulfide formation.Scientific reports · 2025Article
- How Geometric Constraints Control the Hydride Position and Activity in [NiFe]-Hydrogenases and Their Biomimetic Complexes.Inorganic chemistry · 2025Article
- Enhanced Homogeneous Photocatalytic Hydrogen Evolution in a Binuclear Bio-Inspired Ni-Ni Complex Bearing Phenanthroline and Sulfidophenolate Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Pressure-induced generation of heterogeneous electrocatalytic metal hydride surfaces for sustainable hydrogen transfer.Nature communications · 2024Article
- A study on nickel application methods for optimizing soybean growth.Scientific reports · 2024Article
- Development of (NO)Fe(NAccounts of chemical research · 2024Article
- Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes.Chemical communications (Cambridge, England) · 2024Article
- Cyclopentadienyl ring activation in organometallic chemistry and catalysis.Nature reviews. Chemistry · 2023Review
- Electro- and photochemical HSustainable energy & fuels · 2023Article
- Hybrids of [FeFe]- and [NiFe]-HOrganometallics · 2023Article
- Enzymatic and Bioinspired Systems for Hydrogen Production.International journal of molecular sciences · 2023Review
- Characterization of paramagnetic states in an organometallic nickel hydrogen evolution electrocatalyst.Nature communications · 2023Article
- Remarkable Enhancement of Catalytic Activity of Cu-Complexes in the Electrochemical Hydrogen Evolution Reaction by Using Triply Fused Porphyrin.ChemSusChem · 2023Article
- Second and Outer Coordination Sphere Effects in Nitrogenase, Hydrogenase, Formate Dehydrogenase, and CO Dehydrogenase.Chemical reviews · 2022Review
Corrections and comments
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Authors and funding
10 authors at 7 institutions in 5 countries.
Funding
Abstract
Hydrogen production through water splitting is one of the most promising solutions for the storage of renewable energy. [NiFe] hydrogenases are organometallic enzymes containing nickel and iron centres that catalyse hydrogen evolution with performances that rival those of platinum. These enzymes provide inspiration for the design of new molecular catalysts that do not require precious metals. However, all heterodinuclear NiFe models reported so far do not reproduce the Ni-centred reactivity found at the active site of [NiFe] hydrogenases. Here, we report a structural and functional NiFe mimic that displays reactivity at the Ni site. This is shown by the detection of two catalytic intermediates that reproduce structural and electronic features of the Ni-L and Ni-R states of the enzyme during catalytic turnover. Under electrocatalytic conditions, this mimic displays high rates for H
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.