ArticleNature2016
Amide-directed photoredox-catalysed C-C bond formation at unactivated sp
Article in Nature, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 128 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
128 citing papers in PubMed.
- Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity-Matched N-Radical Cations.Angewandte Chemie (International ed. in English) · 2026Article
- An alkyl-swap platform for late-stage modification of secondary N-methylamines.Nature chemistry · 2026Article
- Formal Hydride Abstraction: A Unified Photoredox Platform for Nucleophilic C(sp3)-H Functionalization.Accounts of chemical research · 2026Article
- Direct δ-Lactone Synthesis From Free Alcohols via Photoinduced δ-C(spAngewandte Chemie (International ed. in English) · 2026Article
- Photoredox-Catalyzed Lysine C(spJournal of the American Chemical Society · 2026Article
- Nickel-Catalyzed α‑Arylation and Alkenylation of α‑Trifluoromethyl Amines via 1,2-HAT Assisted by DMSO.JACS Au · 2026Article
- Caging the Chlorine Radical: Chemoselective Photocatalytic C(spJournal of the American Chemical Society · 2026Article
- Article
- COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Vinyl cyclopropanes as a unifying platform for enantioselective remote difunctionalization of alkenes.Nature communications · 2025Article
- Enantioconvergent Chan-Lam Coupling: Synthesis of Chiral Benzylic Amides via Cu-Catalyzed Deborylative Amidation.Journal of the American Chemical Society · 2025Article
- Enhanced Photoredox Activity in Nitrogen-Doped Carbon Nitride for Heterogeneous Nitrogen and Oxygen Radical Reactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Copper(I)-Photocatalyzed Addition of Trichloromethanesulfenyl Chloride to Olefinic Compounds.Molecules (Basel, Switzerland) · 2025Article
- Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer.Beilstein journal of organic chemistry · 2025Review
- Radical-triggered translocation of C-C double bond and functional group.Nature chemistry · 2024Article
- Bidirectional Electron Transfer Strategies for Anti-Markovnikov Olefin Aminofunctionalization via Arylamine Radicals.ACS catalysis · 2024Article
- Sulfonamide-directed site-selective functionalization of unactivated C(spNature communications · 2024Article
- Alkoxy Radical Generation Mediated by Sulfoxide Cation Radicals for Alcohol-Directed Aliphatic C-H Functionalization.Journal of the American Chemical Society · 2024Article
- Photoredox-catalyzed intramolecular nucleophilic amidation of alkenes with β-lactams.Beilstein journal of organic chemistry · 2024Article
- Acceptorless cross-dehydrogenative coupling for C(spCommunications chemistry · 2023Article
68 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
Carbon-carbon (C-C) bond formation is paramount in the synthesis of biologically relevant molecules, modern synthetic materials and commodity chemicals such as fuels and lubricants. Traditionally, the presence of a functional group is required at the site of C-C bond formation. Strategies that allow C-C bond formation at inert carbon-hydrogen (C-H) bonds enable access to molecules that would otherwise be inaccessible and the development of more efficient syntheses of complex molecules. Here we report a method for the formation of C-C bonds by directed cleavage of traditionally non-reactive C-H bonds and their subsequent coupling with readily available alkenes. Our methodology allows for amide-directed selective C-C bond formation at unactivated sp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.