ArticleACS central science2016
Diffusion-Controlled Rotation of Triptycene in a Metal-Organic Framework (MOF) Sheds Light on the Viscosity of MOF-Confined Solvent.
Article in ACS central science, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Turn-on luminescence from molecular rotor realignment in metal-organic framework thin films.Nature communications · 2026Article
- Supramolecular Chemistry in Metal-Organic Framework Materials.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Bifurcated Polymorphic Transition and Thermochromic Fluorescence of a Molecular Crystal Involving Three-Dimensional Supramolecular Gear Rotation.Journal of the American Chemical Society · 2024Article
- Functional dynamics in framework materials.Communications chemistry · 2023Review
- Directing the Self-Assembly of Aromatic Foldamer Helices using Acridine Appendages and Metal Coordination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Controlling dynamics in extended molecular frameworks.Nature reviews. Chemistry · 2022Review
- Translational dynamics of a non-degenerate molecular shuttle imbedded in a zirconium metal-organic framework.Chemical science · 2021Article
- Correlated motion and mechanical gearing in amphidynamic crystalline molecular machines.Chemical science · 2020Review
- Multiple rotational rates in a guest-loaded, amphidynamic zirconia metal-organic framework.Chemical science · 2020Article
- Visible-Light-Driven Rotation of Molecular Motors in a Dual-Function Metal-Organic Framework Enabled by Energy Transfer.Journal of the American Chemical Society · 2020Article
- Hydrogen-Bonding Linkers Yield a Large-Pore, Non-Catenated, Metal-Organic Framework with pcu Topology.Molecules (Basel, Switzerland) · 2020Article
- Rotational Dynamics of Linkers in Metal⁻Organic Frameworks.Nanomaterials (Basel, Switzerland) · 2019Review
- Synthesis of dipolar molecular rotors as linkers for metal-organic frameworks.Beilstein journal of organic chemistry · 2019Article
- Computational Design of Functionalized Metal-Organic Framework Nodes for Catalysis.ACS central science · 2018Review
- Ultrathin two-dimensional porous organic nanosheets with molecular rotors for chemical sensing.Nature communications · 2017Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Artificial molecular machines are expected to operate under conditions of very low Reynolds numbers with inertial forces orders of magnitude smaller than viscous forces. While these conditions are relatively well understood in bulk fluids, opportunities to assess the role of viscous forces in confined crystalline media are rare. Here we report one such example of diffusion-controlled rotation in crystals and its application as a probe for viscosity of MOF-confined solvent. We describe the preparation and characterization of three pillared paddlewheel MOFs, with 9,10-bis(4-pyridylethynyl)triptycene
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