Evidence map›Paper›PMID 27711898›Full record

ArticleFaraday discussions2016

Imaging ultrafast excited state pathways in transition metal complexes by X-ray transient absorption and scattering using X-ray free electron laser source.

Lin X Chen, Megan L Shelby, Patrick J Lestrange, Nicholas E Jackson, Kristoffer Haldrup, Michael W Mara, Andrew B Stickrath, Diling Zhu, Henrik Lemke, Matthieu Chollet and 2 more

Abstract read
In one paragraph

Article in Faraday discussions, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Local vs Nonlocal States in FeTiOInorganic chemistry · 2017
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Lin X ChenChemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois, USA. lchen@anl.gov and Department of Chemistry, Northwestern University, Evanston, Illinois, USA. l-chen@northwestern.edu.
Megan L ShelbyChemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois, USA. lchen@anl.gov and Department of Chemistry, Northwestern University, Evanston, Illinois, USA. l-chen@northwestern.edu.
Patrick J LestrangeDepartment of Chemistry, University of Washington, Seattle, WA 98195, USA.
Nicholas E JacksonChemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois, USA. lchen@anl.gov and Department of Chemistry, Northwestern University, Evanston, Illinois, USA. l-chen@northwestern.edu.
Kristoffer HaldrupPhysics Department, Technical University of Denmark, 2800 Kgs. Lyngby, Denmark.
Michael W MaraDepartment of Chemistry, Northwestern University, Evanston, Illinois, USA. l-chen@northwestern.edu.
Andrew B StickrathChemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois, USA. lchen@anl.gov.
Diling ZhuLCLS, SLAC National Laboratory, Menlo Park, CA 94025, USA.
Henrik LemkeLCLS, SLAC National Laboratory, Menlo Park, CA 94025, USA.
Matthieu CholletLCLS, SLAC National Laboratory, Menlo Park, CA 94025, USA.
Brian M HoffmanDepartment of Chemistry, Northwestern University, Evanston, Illinois, USA. l-chen@northwestern.edu.
Xiaosong LiDepartment of Chemistry, University of Washington, Seattle, WA 98195, USA.

Funding

ELECTRON TRANSFER WITHIN PROTEIN COMPLEXESR01HL063203 · NHLBI · NORTHWESTERN UNIVERSITY · PI HOFFMAN, BRIAN M · 1999 to 2016
$5.8M
Molecular Biophysics Training Program at Northwestern UniversityT32GM008382 · NIGMS · NORTHWESTERN UNIVERSITY · PI RADHAKRISHNAN, ISHWAR · 1990 to 2020
$4.3M
Capturing Transient Protein Structures on Multiple Spatial and Temporal ScalesR01GM115761 · NIGMS · NORTHWESTERN UNIVERSITY · PI CHEN, LIN X · 2015 to 2023
$3.0M
NHLBI NIH HHS R01 HL063203NIGMS NIH HHS R01 GM115761NIGMS NIH HHS T32 GM008382
6 · The paper itself

Abstract

This report will describe our recent studies of transition metal complex structural dynamics on the fs and ps time scales using an X-ray free electron laser source, Linac Coherent Light Source (LCLS). Ultrafast XANES spectra at the Ni K-edge of nickel(ii) tetramesitylporphyrin (NiTMP) were measured for optically excited states at a timescale from 100 fs to 50 ps, providing insight into its sub-ps electronic and structural relaxation processes. Importantly, a transient reduced state Ni(i) (π, 3d

Indexed as

Coordination ComplexesElectronsLasersMolecular ConformationPorphyrinsQuantum TheoryX-RaysCoordination ComplexesPorphyrins

Identifiers

PMID27711898
PMCPMC5177475

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.