Evidence map›Paper›PMID 27656776›Full record

ArticleJournal of the American Chemical Society2016

Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.

Sumit Sahu, Bo Zhang, Christopher J Pollock, Maximilian Dürr, Casey G Davies, Alex M Confer, Ivana Ivanović-Burmazović, Maxime A Siegler, Guy N L Jameson, Carsten Krebs and 1 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.

0numbers the graph read from it
0cells of the map it votes in
17citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

17 citing papers in PubMed.

  1. Review
  2. An Open-Shell FeJournal of the American Chemical Society · 2025
    Article
  3. Aromatic and aliphatic hydrocarbon hydroxylationDalton transactions (Cambridge, England : 2003) · 2023
    Article
  4. Review
  5. Article
  6. Article
  7. Review
  8. Effects of Noncovalent Interactions on High-Spin Fe(IV)-Oxido Complexes.Journal of the American Chemical Society · 2020
    Article
  9. Article
  10. Article
  11. Structural implications of the paramagnetically shifted NMR signals from pyridine H atoms on synthetic nonheme FeJournal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2019
    Article
  12. Review
  13. Article
  14. Article
  15. Article
  16. Selectivity of C-H versus C-F Bond Oxygenation by Homo- and Heterometallic FeChemistry (Weinheim an der Bergstrasse, Germany) · 2017
    Article
  17. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Sumit SahuDepartment of Chemistry, The Johns Hopkins University , 3400 North Charles Street, Baltimore, Maryland 21218, United States.
Bo Zhang
Christopher J Pollock
Maximilian DürrDepartment of Chemistry and Pharmacy, University of Erlangen-Nürnberg , 91058 Erlangen, Germany.
Casey G DaviesDepartment of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago , PO Box 56, Dunedin 9054, New Zealand.
Alex M ConferDepartment of Chemistry, The Johns Hopkins University , 3400 North Charles Street, Baltimore, Maryland 21218, United States.
Ivana Ivanović-BurmazovićDepartment of Chemistry and Pharmacy, University of Erlangen-Nürnberg , 91058 Erlangen, Germany.
Maxime A SieglerDepartment of Chemistry, The Johns Hopkins University , 3400 North Charles Street, Baltimore, Maryland 21218, United States.
Guy N L JamesonDepartment of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago , PO Box 56, Dunedin 9054, New Zealand.
Carsten Krebs
David P GoldbergDepartment of Chemistry, The Johns Hopkins University , 3400 North Charles Street, Baltimore, Maryland 21218, United States.

Funding

Synthetic Nonheme Iron O2 Activation and S-OxygenationR01GM119374 · NIGMS · JOHNS HOPKINS UNIVERSITY · PI GOLDBERG, DAVID P · 2016 to 2023
$3.2M
Synthetic Models of N/S-Ligated Metal Centers in BiologyR01GM062309 · NIGMS · JOHNS HOPKINS UNIVERSITY · PI GOLDBERG, DAVID P · 2001 to 2010
$2.2M
NIGMS NIH HHS R01 GM062309NIGMS NIH HHS R01 GM119374
6 · The paper itself

Abstract

The synthesis and reactivity of a series of mononuclear nonheme iron complexes that carry out intramolecular aromatic C-F hydroxylation reactions is reported. The key intermediate prior to C-F hydroxylation, [Fe

Identifiers

PMID27656776
PMCPMC5628738

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.