ArticleNature communications2016
A switchable self-assembling and disassembling chiral system based on a porphyrin-substituted phenylalanine-phenylalanine motif.
Article in Nature communications, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
22 citing papers in PubMed.
- Fmoc-Phe : Fmoc-Leu supramolecular hydrogels with adaptive antibacterial activity.RSC advances · 2026Article
- Modulation of Self-Assembly and Enhanced Photocatalytic HChemSusChem · 2025Article
- Interaction of Aromatic Amino Acids with Metal Complexes of Tetrakis-(4-Sulfonatophenyl)Porphyrin.Molecules (Basel, Switzerland) · 2024Article
- Advancements in Biosensors Based on the Assembles of Small Organic Molecules and Peptides.Biosensors · 2023Review
- Self-assembled short peptides: Recent advances and strategies for potential pharmaceutical applications.Materials today. Bio · 2023Review
- Kinetic Investigations on the Chiral Induction by Amino Acids in Porphyrin J-Aggregates.International journal of molecular sciences · 2023Article
- Structural and photoactive properties of self-assembled peptide-based nanostructures and their optical bioapplication in food analysis.Journal of advanced research · 2023Review
- Self-Organization of Porphyrin-POM Dyads: Nonplanar Diacids and Oxoanions in Low-Dimensional H-Bonding Networks.Molecules (Basel, Switzerland) · 2022Article
- Versatile Synthesis of Multivalent Porphyrin-Peptide Conjugates by Direct Porphyrin Construction on Resin.Angewandte Chemie (International ed. in English) · 2022Article
- Hierarchical self-assembly of aromatic peptide conjugates into supramolecular polymers: it takes two to tango.Chemical science · 2022Review
- Article
- Peptide-Tetrapyrrole Supramolecular Self-Assemblies: State of the Art.Molecules (Basel, Switzerland) · 2021Review
- Target-driven supramolecular self-assembly for selective amyloid-β photooxygenation against Alzheimer's disease.Chemical science · 2020Article
- Light polarization dependency existing in the biological photosystem and possible implications for artificial antenna systems.Photosynthesis research · 2020Review
- En Route to a Chiral Melanin: The Dynamic "From-Imprinted-to-Template" Supramolecular Role of Porphyrin Hetero-Aggregates During the Oxidative Polymerization of L-DOPA.Frontiers in chemistry · 2020Article
- Photoactive properties of supramolecular assembled short peptides.Chemical Society reviews · 2019Review
- Antenna-like Ring Structures via Self-Assembly of Octaphosphonate Tetraphenyl Porphyrin with Nucleobases.ACS omega · 2019Article
- Conformer-dependent self-assembled metallacycles with photo-reversible response.Chemical science · 2019Article
- Chiral Recognition of L- and D- Amino Acid by Porphyrin Supramolecular Aggregates.Molecules (Basel, Switzerland) · 2018Article
- Multicomponent peptide assemblies.Chemical Society reviews · 2018Review
Corrections and comments
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Authors and funding
18 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Artificial light-harvesting systems have until now not been able to self-assemble into structures with a large photon capture cross-section that upon a stimulus reversibly can switch into an inactive state. Here we describe a simple and robust FLFL-dipeptide construct to which a meso-tetraphenylporphyrin has been appended and which self-assembles to fibrils, platelets or nanospheres depending on the solvent composition. The fibrils, functioning as quenched antennas, give intense excitonic couplets in the electronic circular dichroism spectra which are mirror imaged if the unnatural FDFD-analogue is used. By slightly increasing the solvent polarity, these light-harvesting fibres disassemble to spherical structures with silent electronic circular dichroism spectra but which fluoresce. Upon further dilution with the nonpolar solvent, the intense Cotton effects are recovered, thus proving a reversible switching. A single crystal X-ray structure shows a head-to-head arrangement of porphyrins that explains both their excitonic coupling and quenched fluorescence.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.