ReviewTopics in current chemistry (Cham)2016
Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.
Review in Topics in current chemistry (Cham), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 67 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
67 citing papers in PubMed.
- Net fluorine atom transfer from the perspective of a PCET chemist.Chemical communications (Cambridge, England) · 2026Review
- Mapping Proton-Coupled Electron Transfer With Real Space Coordinates.Angewandte Chemie (International ed. in English) · 2026Article
- Redox-protonation landscape of indene-annulated perylenes: chemodivergent switching of multistate NIR chromophores.Chemical science · 2026Article
- Overcoming the Barrier to Intermolecular Alkoxy Radical Reactivity: Proton-Coupled Electron Transfer-Mediated Alkene Hydroetherification.Journal of the American Chemical Society · 2026Article
- Multisite Proton-Coupled Electron Transfer at a Keggin-Type Polyoxotungstate.Journal of the American Chemical Society · 2026Article
- Tunable Multisite Proton-Coupled Electron Transfer Mediators: Distinct Pathways for Substrate Reduction Versus Competing Hydrogen Evolution.Journal of the American Chemical Society · 2026Article
- Antimicrobial and antioxidant activities of neem assisted silver-modified zeolite X synthesized from kaolin.PloS one · 2026Article
- Sustainable Approaches for the Protection and Deprotection of Functional Groups.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Enhanced Photocatalytic Proton-Coupled Electron Transfer by Ligand Design in a Zr Coordination Cage.ChemSusChem · 2025Article
- Activation and C-C Coupling of Aryl Iodides via Bismuth Photocatalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Photocatalysis and photochemistry in organic synthesis.Beilstein journal of organic chemistry · 2025Article
- Proton Tunneling Allows a Proton-Coupled Electron Transfer Process in the Cancer Cell.JACS Au · 2024Article
- Visible Light-Driven Excited-State Copper-BINAP Catalysis for Accessing Diverse Chemical Reactions.Chem catalysis · 2024Article
- Palladium-catalyzed three-component radical-polar crossover carboamination of 1,3-dienes or allenes with diazo esters and amines.Beilstein journal of organic chemistry · 2024Article
- Photochemical reactions of biomass derived platform chemicals.Frontiers in chemistry · 2024Review
- Density functional theory and machine learning for electrochemical square-scheme prediction: an application to quinone-type molecules relevant to redox flow batteries.Digital discovery · 2023Article
- Advancing electrocatalytic nitrogen fixation: insights from molecular systems.Faraday discussions · 2023Article
- Independent Tuning of the pInorganic chemistry · 2023Article
- Photocatalytic Transformation of Biomass and Biomass Derived Compounds-Application to Organic Synthesis.Molecules (Basel, Switzerland) · 2023Review
- Bis(2,6-pyrazolyl)pyridines as a New Scaffold for Coordination Polymers.Molecules (Basel, Switzerland) · 2023Article
7 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Proton-coupled electron transfers (PCETs) are unconventional redox processes in which both protons and electrons are exchanged, often in a concerted elementary step. While PCET is now recognized to play a central a role in biological redox catalysis and inorganic energy conversion technologies, its applications in organic synthesis are only beginning to be explored. In this chapter, we aim to highlight the origins, development, and evolution of the PCET processes most relevant to applications in organic synthesis. Particular emphasis is given to the ability of PCET to serve as a non-classical mechanism for homolytic bond activation that is complimentary to more traditional hydrogen atom transfer processes, enabling the direct generation of valuable organic radical intermediates directly from their native functional group precursors under comparatively mild catalytic conditions. The synthetically advantageous features of PCET reactivity are described in detail, along with examples from the literature describing the PCET activation of common organic functional groups.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.