ArticlePhysical chemistry chemical physics : PCCP2016
Electron spin dynamics and spin-lattice relaxation of trityl radicals in frozen solutions.
Article in Physical chemistry chemical physics : PCCP, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed, 53 citations in OpenAlex.
- Enlarging Quantum Coherence of Vanadyl Spin Qubits in Zirconium Porphyrinic MOFs.Inorganic chemistry · 2026Article
- High-Fidelity quantum teleportation mediated by hole transfer in an acceptor-donor-radical molecular triad.Nature communications · 2026Article
- Paramagnetic Agents for SE DNP: Synthesis and ESR Characterization of New Lipophilic Derivatives of Finland Trityl.Molecules (Basel, Switzerland) · 2025Article
- Stable organic radical qubits and their applications in quantum information science.Innovation (Cambridge (Mass.)) · 2024Review
- Large-enhancement nanoscale dynamic nuclear polarization near a silicon nanowire surface.Science advances · 2024Article
- Deconvoluting Monomer- and Dimer-Specific Distance Distributions between Spin Labels in a Monomer/Dimer Mixture UsingJournal of the American Chemical Society · 2024Article
- Article
- PDI-trityl dyads as photogenerated molecular spin qubit candidates.Chemical science · 2023Article
- PyrroTriPol: a semi-rigid trityl-nitroxide for high field dynamic nuclear polarization.Chemical science · 2023Article
- Reverse dynamic nuclear polarisation for indirect detection of nuclear spins close to unpaired electrons.Magnetic resonance (Gottingen, Germany) · 2022Article
- Cleavage-Resistant Protein Labeling With Hydrophilic Trityl Enables Distance MeasurementsThe journal of physical chemistry. B · 2021Article
- Excitation Energy Transfer and Exchange-Mediated Quartet State Formation in Porphyrin-Trityl Systems.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- In Situ Labeling and Distance Measurements of Membrane Proteins in E. coli Using Finland and OX063 Trityl Labels.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Trehalose as an alternative to glycerol as a glassing agent for in vivo DNP MRI.Magnetic resonance in medicine · 2021Article
- Structural insights for vanadium catecholates and iron‑sulfur clusters obtained from multiple data analysis methods applied to electron spin relaxation data.Journal of inorganic biochemistry · 2019Article
- Metal-ligand covalency enables room temperature molecular qubit candidates.Chemical science · 2019Article
- A high-spin ground-state donor-acceptor conjugated polymer.Science advances · 2019Article
- A concentrated array of copper porphyrin candidate qubits.Chemical science · 2019Article
- Maximizing NMR signal per unit time by facilitating the e-e-n cross effect DNP rate.Physical chemistry chemical physics : PCCP · 2018Article
Corrections and comments
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Authors and funding
6 authors at 3 institutions in 2 countries.
Funding
Abstract
Electron spin-lattice relaxation of two trityl radicals, d24-OX063 and Finland trityl, were studied under conditions relevant to their use in dissolution dynamic nuclear polarization (DNP). The dependence of relaxation kinetics on temperature up to 100 K and on concentration up to 60 mM was obtained at X- and W-bands (0.35 and 3.5 Tesla, respectively). The relaxation is quite similar at both bands and for both trityl radicals. At concentrations typical for DNP, relaxation is mediated by excitation transfer and spin-diffusion to fast-relaxing centers identified as triads of trityl radicals that spontaneously form in the frozen samples. These centers relax by an Orbach-Aminov mechanism and determine the relaxation, saturation and electron spin dynamics during DNP.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.